Diorganotin complexes of carboxylates: synthesis and characterization

被引:8
|
作者
Chilwal, Asha [1 ]
Deep, Gagan [2 ]
Malhotra, Priti [3 ]
Narula, A. K. [1 ]
机构
[1] Guru Gobind Singh Indraprastha Univ, Sch Basic & Appl Sci, Delhi, India
[2] Lovely Profess Univ, Dept Chem, Sch Sci, Jalandhar, Punjab, India
[3] Univ Delhi, Daulat Ram Coll, Dept Chem, New Delhi, India
关键词
Synthesis; Characterization; Organotin compounds; IN-VITRO ANTIBACTERIAL; ORGANOTIN(IV) COMPLEXES; DERIVATIVES; C-13;
D O I
10.1080/00958972.2013.775428
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Diorganotin complexes of monoisopropyl and monomethyl nadiate, succinate, and phthalate were synthesized and characterized by elemental analysis, FT-IR, H-1 NMR, C-13 NMR, and Sn-119 NMR spectroscopic techniques. The spectroscopic investigation demonstrated that carboxylate is bidentate in the diorganotin complexes. On the basis of (1)J(Sn-119-C-13) and (2)J(Sn-119-H-1) values, C-Sn-C bond angles were also calculated. The newly synthesized complexes were also screened for their antibacterial activities against Gram-positive and Gram-negative pathogenic strains of bacteria.
引用
收藏
页码:1046 / 1057
页数:12
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