Helium-hydrogen immiscibility at high pressures

被引:7
|
作者
Wang, Yu [1 ,2 ,3 ]
Zhang, Xiao [1 ,2 ,3 ]
Jiang, Shuqing [1 ,2 ]
Geballe, Zachary M. [4 ]
Pakornchote, Teerachote [4 ,5 ]
Somayazulu, Maddury [4 ]
Prakapenka, Vitali B. [6 ]
Greenberg, Eran [6 ]
Goncharov, Alexander F. [1 ,2 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Ctr Energy Matter Extreme Environm, Hefei 230031, Anhui, Peoples R China
[3] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
[4] Carnegie Inst Sci, Geophys Lab, 5251 Broad Branch Rd, Washington, DC 20015 USA
[5] Chulalongkorn Univ, Dept Phys, Bangkok 10330, Thailand
[6] Univ Chicago, Ctr Adv Radiat Sources, Chicago, IL 60637 USA
来源
JOURNAL OF CHEMICAL PHYSICS | 2019年 / 150卷 / 11期
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
X-RAY-DIFFRACTION; EQUATION-OF-STATE; BINARY PHASE-DIAGRAM; HIGH-TEMPERATURE; INTERIORS; MIXTURES; COMPOUND; JUPITER; SODIUM; POLYHYDRIDES;
D O I
10.1063/1.5086270
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen and helium are the most abundant elements in the universe, and they constitute the interiors of gas giant planets. Thus, their equations of states, phase, chemical state, and chemical reactivity at extreme conditions are of great interest. Applying Raman spectroscopy, visual observation, and synchrotron X-ray diffraction in diamond anvil cells, we performed experiments on H-2-He 1:1 and D-2-He 1:10 compressed gas mixtures up to 100 GPa at 300 K. By comparing with the available data on pure bulk materials, we find no sign of miscibility, chemical reactivity, and new compound formation. This result establishes a new baseline for future investigations of miscibility in the He-H-2 system at extreme P-T conditions. Published under license by AIP Publishing.
引用
收藏
页数:6
相关论文
共 50 条
  • [1] Excitation transfer in a helium-hydrogen plasma
    Skoblo, YE
    Ivanova, VA
    Zhiglinskii, AA
    OPTICS AND SPECTROSCOPY, 1998, 84 (06) : 825 - 827
  • [2] THE HELIUM-HYDROGEN FLUORIDE POTENTIAL SURFACE
    RODWELL, WR
    LAM, LTSF
    WATTS, RO
    MOLECULAR PHYSICS, 1981, 44 (01) : 225 - 240
  • [3] The helium-hydrogen series constants.
    Bell, H
    PHILOSOPHICAL MAGAZINE, 1920, 40 (238): : 489 - 494
  • [4] Electric field measurement in a DBD in helium and helium-hydrogen mixture
    Ivkovic, S. S.
    Obradovic, B. M.
    Kuraica, M. M.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2012, 45 (27)
  • [5] ION MOBILITY IN A HELIUM-HYDROGEN ADMIXTURE
    MELLOR, DJ
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1971, 4 (10) : 1535 - &
  • [6] Extreme ultraviolet spectroscopy of helium-hydrogen plasma
    Mills, R
    Ray, P
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2003, 36 (13) : 1535 - 1542
  • [7] HYDROGEN EXCITED-STATE POPULATIONS IN A HELIUM-HYDROGEN AFTERGLOW
    MARSTAD, NC
    BURNETT, CR
    BULLETIN OF THE AMERICAN PHYSICAL SOCIETY, 1968, 13 (11): : 1559 - &
  • [8] Hydrogen, helium and lithium plasmas at high pressures
    Ebeling, Werner
    Reinholz, Heidi
    Roepke, Gerd
    EUROPEAN PHYSICAL JOURNAL-SPECIAL TOPICS, 2020, 229 (22-23): : 3403 - 3431
  • [9] Hydrogen, helium and lithium plasmas at high pressures
    Werner Ebeling
    Heidi Reinholz
    Gerd Röpke
    The European Physical Journal Special Topics, 2020, 229 : 3403 - 3431
  • [10] THERMODYNAMICS OF HYDROGEN AND HELIUM AT HIGH-PRESSURES
    MASLENNIKOVA, VY
    GAVRILOV, SD
    TSIKLIS, DS
    ZHURNAL FIZICHESKOI KHIMII, 1975, 49 (09): : 2435 - 2437