Highly efficient hydrolysis of ammonia borane by anion (-OH, F-, Cl-)-tuned interactions between reactant molecules and CoP nanoparticles

被引：104

作者：

Fu, Zi-Cheng ^{[1
,2
]}

Xu, Yong ^{[1
,2
]}

Chan, Sharon Lai-Fung ^{[3
]}

Wang, Wei-Wei

Li, Fang ^{[1
,2
]}

Liang, Fei ^{[1
,2
]}

Chen, Yong ^{[1
,2
]}

Lin, Zhe-Shuai ^{[1
,2
]}

Fu, Wen-Fu ^{[1
,2
,4
]}

Che, Chi-Ming ^{[5
]}

机构：

[1] Chinese Acad Sci, Key Lab Photochem Convers & Optoelect Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, HKU CAS Joint Lab New Mat, Tech Inst Phys & Chem, Beijing 100190, Peoples R China

[3] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hong Kong, Hong Kong, Peoples R China

[4] Yunnan Normal Univ, Coll Chem & Engn, Kunming 650092, Peoples R China

[5] Univ Hong Kong, Dept Chem, Pokfulam Rd, Hong Kong, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 04期

基金：

中国国家自然科学基金;

关键词：

HIGH CATALYTIC-ACTIVITY; HYDROGEN GENERATION; DEHYDROGENATION; WATER; SIZE; IRRADIATION; PERFORMANCE; REDUCTION; STORAGE;

D O I：

10.1039/c6cc08120g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The CoP nanoparticle catalyst had excellent catalytic activity and a short catalytic induction period in the presence of anions, and high sustainability in ammonia borane hydrolysis, with an initial turnover frequency of 72.2 mol((H2)) mol((CoP))-(1) min(-1) at ambient temperature. This value is unprecedented for noble-metal-free catalytic systems.

引用

页码：705 / 708

页数：4

共 3 条

[1] Oxygen modified CoP2 supported palladium nanoparticles as highly efficient catalyst for hydrolysis of ammonia borane
Leijie Zhang
Jian Ye
Yi Tu
Qingyu Wang
Haibin Pan
Lihui Wu
Xusheng Zheng
Junfa Zhu
Nano Research, 2022, 15 : 3034 - 3041
[2] Oxygen modified CoP2 supported palladium nanoparticles as highly efficient catalyst for hydrolysis of ammonia borane
Zhang, Leijie
Ye, Jian
Tu, Yi
Wang, Qingyu
Pan, Haibin
Wu, Lihui
Zheng, Xusheng
Zhu, Junfa
NANO RESEARCH, 2022, 15 (04) : 3034 - 3041
[3] Ultrafast hydrogen generation from the hydrolysis of ammonia borane catalyzed by highly efficient bimetallic RuNi nanoparticles stabilized on Ti3C2X2 (X = OH and/or F)
Li, Xiaojing
Zeng, Chunmei
Fan, Guangyin
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (10) : 3883 - 3891

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