Synthesis of O,O-Diethyl Arylthiophosphonate from O-Aryl-O,O-diethylthiophosphate

被引:8
|
作者
Dieng, Thierno [1 ]
Fraix, Aurore [1 ]
Salauen, Jean-Yves [1 ]
Dez, Isabelle [2 ]
Gebbink, Robertus. J. M. Klein [3 ]
van Koten, Gerard [3 ]
Jaffres, Paul-Alain [1 ]
机构
[1] Univ Europeennee Bretagne, Fed Rech SclnBios, CNRS UMR 6521 CEMCA, Univ Brest, F-29238 Brest, France
[2] Univ Caen, LCMT, UMR CNRS 6507, ENSICAEN, F-14050 Caen, France
[3] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands
关键词
phosphorylation; metallation; phenols; rearrangement;
D O I
10.1055/s-0028-1087362
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of O,O-diethyl 2-hydroxyarylthiophosphonate is reported by using a [1,3]-rearrangement. This method is achieved in high yield from ortho-bromophenols derivatives by a two-step process
引用
收藏
页码:3121 / 3124
页数:4
相关论文
共 50 条
  • [1] SYNTHESIS OF O-ARYL-O'-ALKYL PHOSPHITES
    MANDELBA.YA
    MELNIKOV, NN
    ITSKOVA, AL
    ZHURNAL OBSHCHEI KHIMII, 1972, 42 (03): : 502 - &
  • [2] STUDIES ON OPTICALLY ACTIVE ISOMERS OF O O-DIETHYL MALATHION AND O O-DIETHYL MALAOXON
    HASSAN, A
    DAUTERMAN, WC
    BIOCHEMICAL PHARMACOLOGY, 1968, 17 (07) : 1431 - +
  • [3] Synthesis of aryldifluoromethylphosphonothioic acids from O,O-diethyl aryldifluoromethylphosphonothioates
    Yokomatsu, T
    Takechi, H
    Murano, T
    Shibuya, S
    JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (18): : 5858 - 5861
  • [4] Analytical method for the determination of O,O-diethyl phosphate and O,O-diethyl thiophosphate in faecal samples
    Schenke, D
    CHEMOSPHERE, 2000, 41 (09) : 1313 - 1320
  • [5] O,O-diethyl phthalimidophosphonothioate (ditalimphos)
    Baughman, RG
    Paulos, CM
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2352 - O2353
  • [6] SYNTHESIS OF O,O-DIETHYL S VINYL PHOSPHOROTHIOATE
    SEMIDETK.VV
    GOLOLOBO.YG
    JOURNAL OF GENERAL CHEMISTRY USSR, 1967, 37 (12): : 2659 - &
  • [7] PROPERTIES OF O,O-DIETHYL O-PARA-NITRO-PHENYL THIOPHOSPHATE AND O,O-DIETHYL O-PARA-NITROPHENYL PHOSPHATE
    WILLIAMS, EF
    INDUSTRIAL AND ENGINEERING CHEMISTRY, 1951, 43 (04): : 950 - 954
  • [8] Simple and efficient synthesis of new O,O-diethyl phosphorothioates
    Pokalwar, R. U.
    Hangarge, R. V.
    Kategaonkar, A. H.
    Shingare, M. S.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2009, 45 (03) : 430 - 433
  • [9] Simple and efficient synthesis of new O,O-diethyl phosphorothioates
    R. U. Pokalwar
    R. V. Hangarge
    A. H. Kategaonkar
    M. S. Shingare
    Russian Journal of Organic Chemistry, 2009, 45 : 430 - 433
  • [10] REACTION OF O,O-DIETHYL PHOSPHOROTHIOITE WITH CHLOROMETHYLSULFENYL SPECIES - PREPARATION OF S-CHLOROMETHYL O,O-DIETHYL PHOSPHORODITHIOATE
    BRAND, WW
    GULLO, JM
    CARR, MC
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1981, 10 (02): : 183 - 184