Inorganic binder-containing composite cathode contact materials for solid oxide fuel cells

被引:23
|
作者
Tucker, Michael C. [1 ]
Cheng, Lei [1 ]
DeJonghe, Lutgard C. [2 ]
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Environm Energy Technol Div, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Div Mat Sci, Berkeley, CA 94720 USA
关键词
Solid oxide fuel cell; Cathode contact material; Inorganic binder; Stainless steel interconnect;
D O I
10.1016/j.jpowsour.2012.09.114
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The feasibility of adding inorganic binder to conventional SOFC cathode contact materials in order to improve bonding to adjacent materials in the cell stack is assessed. A variety of candidate binder compositions are added to LSM. The important properties of the resulting composites, including ASR, reactivity, and adhesion to LSCF and MCO-coated 441 stainless steel are used as screening parameters. The most promising CCM/binder composites are coated onto MCO-coated 441 coupons and anode-supported button cells with LSCF cathode, and tested at 800 degrees C. It is found that a LSM-644A composite displayed excellent initial performance and promising stability. Indeed, addition of binder is found to improve bonding of the CCM layer without sacrificing CCM conductivity. (C) 2012 Elsevier BM. All rights reserved.
引用
收藏
页码:174 / 179
页数:6
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