Synthesis, structure and magnetic property of a new oxo-centered mixed-valent trinuclear manganese complex

被引:15
|
作者
Li, J [1 ]
Zhang, FX
Shi, QZ
Wang, J
Wang, Y
Zhou, ZY
机构
[1] NW Univ Xian, Dept Chem, Xian 710069, Peoples R China
[2] Chinese Acad Sci, Chengdu Inst Organ Chem, Chengdu 610041, Peoples R China
基金
中国国家自然科学基金;
关键词
mixed-valent; trinuclear manganese complex; crystal structure; preparation;
D O I
10.1016/S1387-7003(01)00333-1
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A mixed-valent trinuclear mu(3)-oxo bridged manganese complex [Mn3O(O2CCH2Cl)(6)(Py)(2)(H2O)] . 0.5C(5)H(5)N was synthesized. Its crystal structure was determined, together with the results of variable temperature magnetic susceptibility, cyclic voltammogram and IR spectrum. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:51 / 55
页数:5
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