A New Star-shaped Carbazole Derivative with Polyhedral Oligomeric Silsesquioxane Core: Crystal Structure and Unique Photoluminescence Property

被引：27

作者：

Xu, Zixuan ^{[1
]}

Yu, Tianzhi ^{[1
]}

Zhao, Yuling ^{[2
]}

Zhang, Hui ^{[1
]}

Zhao, Guoyun ^{[2
]}

Li, Jianfeng ^{[1
]}

Chai, Lanqin ^{[2
]}

机构：

[1] Lanzhou Jiaotong Univ, Minist Educ, Key Lab Optoelect Technol & Intelligent Control, Lanzhou 730070, Peoples R China

[2] Lanzhou Jiaotong Univ, Sch Chem & Biol Engn, Lanzhou 730070, Peoples R China

来源：

JOURNAL OF FLUORESCENCE | 2016年 / 26卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Polyhedral oligomeric silsesquioxane; Carbazole derivative; Crystal structure; Photoluminescence; POLYFLUORENES;

D O I：

10.1007/s10895-015-1694-y

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A new inorganic-organic hybrid material based on polyhedral oligomeric silsesquioxane (POSS) capped with carbazolyl substituents, octakis[3-(carbazol-9-yl)propyldimethylsiloxy]-silsesquioxane (POSS-8Cz), was successfully synthesized and characterized. The X-ray crystal structure of POSS-8Cz were described. The photophysical properties of POSS-8Cz were investigated by using UV-vis, photoluminescence spectroscopic analysis. The hybrid material exhibits blue emission in the solution and the solid film. The morphology and thermal stablity properties were measured by X-ray diffraction (XRD) and TG-DTA analysis.

引用

页码：149 / 154

页数：6

共 25 条

[1] A New Star-shaped Carbazole Derivative with Polyhedral Oligomeric Silsesquioxane Core: Crystal Structure and Unique Photoluminescence Property
Zixuan Xu
Tianzhi Yu
Yuling Zhao
Hui Zhang
Guoyun Zhao
Jianfeng Li
Lanqin Chai
Journal of Fluorescence, 2016, 26 : 149 - 154
[2] Star-shaped poly(ε-caprolactone) with polyhedral oligomeric silsesquioxane core
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Yang, Xingtian
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[3] Star-Shaped Molecules with Polyhedral Oligomeric Silsesquioxane Core and Azobenzene Dye Arms
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Tkachenko, Ihor M.
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[4] Star-Shaped Quaternary Alkylammonium Polyhedral Oligomeric Silsesquioxane Ionic Liquids
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[5] Synthesis, characterization and surface properties of star-shaped polymeric surfactants with polyhedral oligomeric silsesquioxane core
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[6] Surface Segregation of a Star-Shaped Polyhedral Oligomeric Silsesquioxane in a Polymer Matrix
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Abe, Tatsuki
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LANGMUIR, 2020, 36 (33) : 9960 - 9966
[7] Synthesis and characterization of star-shaped block copolymers with polyhedral oligomeric silsesquioxane (POSS)core via ATRP
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Ming Fei
Xiaoxiao Jie
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[8] Synthesis and characterization of star-shaped block copolymers with polyhedral oligomeric silsesquioxane (POSS)core via ATRP
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POLYMER BULLETIN, 2010, 65 (09) : 863 - 872
[9] Star-shaped polyhedral oligomeric silsesquioxane-polycaprolactone-polyurethane as biomaterials for tissue engineering application
Choon Peng Teng
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Khin Yin Win
Chee Chuan Yeo
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NPG Asia Materials, 2014, 6 : e142 - e142
[10] Star-shaped polyhedral oligomeric silsesquioxane-polycaprolactone-polyurethane as biomaterials for tissue engineering application
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Mya, Khine Yi
Win, Khin Yin
Yeo, Chee Chuan
Low, Michelle
He, Chaobin
Han, Ming-Yong
NPG ASIA MATERIALS, 2014, 6 : e142 - e142

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