An Elastic, Conductive, Electroactive Nanocomposite Binder for Flexible Sulfur Cathodes in Lithium-Sulfur Batteries

被引:114
|
作者
Milroy, Craig [1 ]
Manthiram, Arumugam [1 ]
机构
[1] Univ Texas Austin, McKetta Dept Chem Engn, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
COMPOSITE; PERFORMANCE; POLYPYRROLE; ELECTRODE; PAPER;
D O I
10.1002/adma.201601665
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A conductive, elastic, electroactive binder composed of polypyrrole and poly urethane is adopted for flexible, high-loading lithium-sulfur cathodes. The conductivity of the polypyrrole helps mitigate the negative effects of insulating sulfur, and the elastomeric matrix accommodates sulfur volume expansion. The binder is used with a simple carbon/sulfur composite to produce high-performance, flexible electrodes without excessive carbon, interlayers, or special additives.
引用
收藏
页码:9744 / +
页数:9
相关论文
共 50 条
  • [1] MXenes in sulfur cathodes for lithium-sulfur batteries
    Wong, Andrew Jun Yao
    Lieu, Wei Ying
    Yang, Hui Ying
    Seh, Zhi Wei
    JOURNAL OF MATERIALS RESEARCH, 2022, 37 (22) : 3890 - 3905
  • [2] Enhanced cyclability of sulfur cathodes in lithium-sulfur batteries with Na-alginate as a binder
    Weizhai Bao
    Zhian Zhang
    Yongqing Gan
    Xiwen Wang
    Jie Lia
    Journal of Energy Chemistry, 2013, (05) : 790 - 794
  • [3] Enhanced cyclability of sulfur cathodes in lithium-sulfur batteries with Na-alginate as a binder
    Bao, Weizhai
    Zhang, Zhian
    Gan, Yongqing
    Wang, Xiwen
    Lia, Jie
    JOURNAL OF ENERGY CHEMISTRY, 2013, 22 (05) : 790 - 794
  • [4] Enhanced cyclability of sulfur cathodes in lithium-sulfur batteries with Na-alginate as a binder
    Weizhai Bao
    Zhian Zhang
    Yongqing Gan
    Xiwen Wang
    Jie Lia
    Journal of Energy Chemistry, 2013, 22 (05) : 790 - 794
  • [5] Recent progress of sulfur cathodes and other components for flexible lithium-sulfur batteries
    He, Y.
    Bi, S.
    Jiang, C.
    Song, J.
    MATERIALS TODAY SUSTAINABILITY, 2022, 19
  • [6] Kinetic Promoters for Sulfur Cathodes in Lithium-Sulfur Batteries
    Zhao, Meng
    Peng, Hong-Jie
    Li, Bo-Quan
    Huang, Jia-Qi
    ACCOUNTS OF CHEMICAL RESEARCH, 2024, 57 (04) : 545 - 557
  • [7] Poly(3,4-ethylenedioxythiophene)-coated sulfur for flexible and binder-free cathodes of lithium-sulfur batteries
    Zhang, Miao
    Meng, Qinghai
    Ahmad, Aziz
    Mao, Lijuan
    Yan, Wei
    Wei, Zhixiang
    JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (33) : 17647 - 17652
  • [8] Organic Binder for the Lithium-Sulfur Batteries
    Jasso, K.
    Kazda, T.
    Cudek, P.
    19TH INTERNATIONAL CONFERENCE ON ADVANCED BATTERIES, ACCUMULATORS AND FUEL CELLS (ABAF 2018), 2018, 87 (01): : 93 - 97
  • [9] A high-resilience and conductive composite binder for lithium-sulfur batteries
    Zheng, Mengyao
    Cai, Xiaomin
    Tan, Yafang
    Wang, Wenqiang
    Wang, Dongya
    Fei, Haojie
    Saha, Petr
    Wang, Gengchao
    CHEMICAL ENGINEERING JOURNAL, 2020, 389
  • [10] Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries
    Liang, Xiao
    Garsuch, Arnd
    Nazar, Linda F.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (13) : 3907 - 3911