A two-dimensional network containing an -MnOCOMn- chain: poly[diaqua[1,2-bis(pyridin-4-yl)ethylene][3-3-carboxy-5-(carboxylatomethoxy)benzoato]manganese(II)]

被引：0
|
作者：
Lei, Yong-Qian [1 ]
Wang, Guan-Hua [1 ]
机构：
[1] Guangdong Inst Anal, Guangdong Prov Publ Lab Anal & Testing Technol, Guangzhou 510070, Guangdong, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2013年 / 69卷
基金：
中国国家自然科学基金;
关键词：
crystal structure; two-dimensional polymeric structures; manganese compounds; 5-(carboxymethoxy)isophthalic acid; COORDINATION POLYMERS; FRAMEWORKS;
D O I：
10.1107/S0108270113025377
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the title compound, [Mn(C10H6O7)(C12H10N2)(H2O)2]n or [Mn(HOABDC)(bpe)(H2O)2]n [H3OABDC is 5-(carboxymethoxy)isophthalic acid and bpe is 1,2-bis(pyridin-4-yl)ethylene], each MnII cation is at the centre of a distorted octahedron formed by three carboxylate O atoms from three different HOABDC2- ligands, one pyridyl N atom from the terminal bpe ligand and two water molecules. The flexible oxyacetate group bound to a methylene C atom of the HOABDC2- ligand links the MnII centres into -MnOCOMn- chains, and the carboxylate group bound directly to the benzene ring extends the chains into two-dimensional layers which lie parallel to the (010) plane and present herringbone patterns. Intermolecular OH...N and CH...O hydrogen bonds connect the layers into a three-dimensional supramolecular structure.
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收藏
页码：1311 / +
页数：8
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