Pressure quenching: a new route for the synthesis of black phosphorus

被引：18

作者：

Sun, Qiushi ^{[1
]}

Zhao, Xudong ^{[1
]}

Feng, Yi ^{[1
]}

Wu, Yunpeng ^{[1
]}

Zhang, Ziqing ^{[1
]}

Zhang, Xinyang ^{[1
]}

Wang, Xiaofeng ^{[1
]}

Feng, Shouhua ^{[1
]}

Liu, Xiaoyang ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China

来源：

INORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 03期

基金：

中国国家自然科学基金;

关键词：

SINGLE-CRYSTALS; PHASE; TRANSITIONS; SILICON;

D O I：

10.1039/c7qi00775b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Methods to synthesize black phosphorus (BP) have been studied over the last few decades with several challenges remaining to be solved. In this paper, BP flakes were synthesized using a novel method, which we named as " Pressure Quenching" approach. Briefly, BP was obtained from red phosphorus (RP) through a controllable phase transition under conditions below 0.4 GPa and 580 degrees C. The mechanism was investigated in detail via a decompression process at fixed temperature with the phase transition exhibiting an energy barrier dependence. Meanwhile, an extra tunable energy was generated by pressure quenching as a supplement for the phase transition. Therefore, the transition from RP to BP could be easily controlled by tuning the applied pressure.

引用

页码：669 / 674

页数：6

共 50 条

[1] In Situ Doping of Black Phosphorus by High-Pressure Synthesis
Antonatos, Nikolas
Bousa, Daniel
Shcheka, Svyatoslav
Beladi-Mousavi, Seyyed Mohsen
Pumera, Martin
Sofer, Zdenek
[J]. INORGANIC CHEMISTRY, 2019, 58 (15) : 10227 - 10238
[2] A NEW ROUTE TO SYNTHESIS OF ROUSSINS-BLACK-SALT
WHARTON, EJ
MCCLEVER.JA
[J]. INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1970, 6 (06): : 549 - &
[3] A fast low-pressure transport route to large black phosphorus single crystals
Nilges, Tom
Kersting, Marcel
Pfeifer, Thorben
[J]. JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (08) : 1707 - 1711
[4] Pentacovalent phosphorus in organic synthesis: A new route to substituted phosphonates
Stacy, Danielle Marie
McClure, Cynthia K.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 234
[5] Pentacovalent phosphorus in organic synthesis: A new route to substituted phosphonates
Stacy, Danielle Marie
Schuff, Brandon
McClure, Cynthia K.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[6] PENTACOVALENT PHOSPHORUS IN ORGANIC-SYNTHESIS - A NEW ROUTE TO SUBSTITUTED PHOSPHONATES
MCCLURE, CK
JUNG, KY
GROTE, CW
HANSEN, K
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 75 (1-4): : 23 - 26
[7] PENTACOVALENT PHOSPHORUS IN ORGANIC-SYNTHESIS - A NEW ROUTE TO SUBSTITUTED PHOSPHONATES
MCCLURE, CK
JUNG, KY
GROTE, C
HANSEN, K
MAYHEW, K
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 246 - ORGN
[8] Synthesis of black phosphorus films
Fortin-Deschenes, Matthieu
Xia, Fengnian
[J]. NATURE MATERIALS, 2023, 22 (06) : 681 - 682
[9] SYNTHESIS OF SEMICONDUCTING BLACK PHOSPHORUS
ELLIS, RC
WARSCHAUER, DM
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1962, 109 (08) : C207 - C207
[10] Synthesis of black phosphorus films
Matthieu Fortin-Deschênes
Fengnian Xia
[J]. Nature Materials, 2023, 22 : 681 - 682

← 1 2 3 4 5 →