Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst

被引：65
|
作者：
Powell, Adam B. [1 ]
Stahl, Shannon S. [1 ]
机构：
[1] Univ Wisconsin, Dept Chem, Madison, WI 53706 USA
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 19期
基金：
美国国家科学基金会;
关键词：
LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; ESTERIFICATION; CONVERSION; ALDEHYDES; OXYGEN; ACIDS; TRANSFORMATION; WATER; LEAD;
D O I：
10.1021/ol402428e
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Efficient aerobic oxidative methyl esterification of primary alcohols has been achieved with a heterogeneous catalyst consisting of 1 mol % Pd/charcoal (5 wt %) in combination with bismuth(III) nitrate and tellurium metal. The Bi and Te additives significantly increase the reaction rate, selectivity, and overall product yields. This readily accessible catalyst system exhibits a broad substrate scope and Is effective with both activated (benzylic) and unactivated (aliphatic) alcohols bearing diverse functional groups.
引用
收藏
页码：5072 / 5075
页数：4
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