CATALYTIC PARTIAL OXIDATION OF NATURAL GAS IN GAS TURBINE APPLICATIONS

The demands of emissions, combustion efficiency over a wider operational range, and fuel flexibility for industrial gas turbine applications are expected to increase in the coming years. Currently, it is common the use of a stabilizing piloting diffusion flame during part load operation, this flame is accountable for an important part of the thermal NOx emissions on partial load, and in some cases also at full load operation. On the other hand Catalytic Partial Oxidation (CPO) of natural gas is a technique used in petrochemical industry for the Fischer-Tropsch process and for H-2 production, and is based in the production of Syn-Gas rich in H-2 and CO. The present work explores the possibility to use the CPO of natural gas in industrial gas turbine applications, it is based in experiments performed between 5 and 13 bar using an arrangement of Rh based catalyst and CH4. The experiments were done at the Catalytic Combustion High Pressure Test Facility, at the Royal Institute of Technology (KTH) in Sweden. The gas produced leaves the CPO reactor between 700 and 850 degrees C and it is rich in H-2 and CO. It was found that the most important parameter after reaching the light off temperature in the CPO reactor is the equivalence ratio Phi, which evidences the kinetically controlled regime in the Rh catalyst that depends on O-2 availability. The H-2/CO ratio is close to the theoretical value of 2 and the selectivity towards H-2 and CO are 90% and 95% respectively while the CH4 conversion reached approximately 55%. Pressure on the other hand had a small negative influence in the tested pressure range and it is more relevant at richer fuel conditions (high equivalence ratios). The CPO process had shown that it is relatively easy to control the operation temperature of the catalyst. This temperature is kept below the maximum allowed by reducing the O-2 availability. The high temperature Syn-Gas gas produced through CPO process could be burnt in the downstream of the catalysts steadily at flame temperatures below the thermal-NOx threshold. The CPO reactor could provide the flame stabilization function at a wide range of operational conditions, and replace the diffusion piloting flame. This approach could cope with NOx and CO emissions in a wider operational range and offers the possibility of using different fuels as the reaction controlling factor is O-2 availability. Furthermore, an initial design of a possible combustion strategy downstream of the CPO reactor is also presented.