Sulfur-based redox chemistry for electrochemical energy storage

被引：36
|
作者：
Huang, Xia [1 ,2 ]
Luo, Bin [1 ,2 ]
Chen, Peng [1 ,2 ]
Searles, Debra J. [3 ,4 ]
Wang, Dan [5 ]
Wang, Lianzhou [1 ,2 ]
机构：
[1] Univ Queensland, Nanomat Ctr, Sch Chem Engn, St Lucia, Qld 4072, Australia
[2] Univ Queensland, Australian Inst Bioengn & Nanotechnol, St Lucia, Qld 4072, Australia
[3] Univ Queensland, Ctr Theoret & Computat Mol Sci, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia
[4] Univ Queensland, Sch Chem & Mol Biosci, Brisbane, Qld 4072, Australia
[5] Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, 1 Beiertiao, Beijing 100190, Peoples R China
来源：
COORDINATION CHEMISTRY REVIEWS | 2020年 / 422卷
基金：
澳大利亚研究理事会; 中国国家自然科学基金;
关键词：
Electrochemical energy storage; Anionic redox; Cationic redox; Sulfur; Metal (poly)sulfides; Polymerized sulfur; ALL-SOLID-STATE; LITHIUM-SULFUR; LI-S; CATHODE MATERIAL; ELECTRODE MATERIALS; ELEMENTAL SULFUR; ANIONIC REDOX; HIGH-CAPACITY; POLYMERIZATION ELECTRODES; RECHARGEABLE BATTERIES;
D O I：
10.1016/j.ccr.2020.213445
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The burgeoning developments of portable electronics and electric vehicles call for continual improvement of electrochemical energy storage technologies. Owing to their rich abundance and versatile oxidation states, various sulfur species (such as molecular sulfur, metal sulfides, metal polysulfides, and polymerised sulfur species) have been studied in a wide spectrum of energy storage systems. In this review, sulfur-based redox chemistries for electrochemical energy storage are coherently analysed, covering the redox mechanism of processes based on conversion, intercalation/deintercalation, cleavage/formation of S-S bonds and combinations of them. Instead of updating the advances of a specific battery system or material, this review focuses on a comprehensive framework for sulfur-based redox chemistries in electrochemical energy storage. Innovative ideas may arise by sharing learning between related areas. (C) 2020 Elsevier B.V. All rights reserved.
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页数：26
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