Tuning the entanglement of coordination polymers by controlling the steric hindrance of organic linkers

被引：3
|
作者：
Guo, Xianmin [1 ]
Guo, Huadong [1 ]
Zou, Hengye [1 ]
Qi, Yanjuan [1 ]
Liu, Chunming [1 ]
机构：
[1] Changchun Normal Univ, Dept Chem, Changchun 130032, Peoples R China
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2013年 / 1043卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymers; Entanglement; Steric hindrance; LUMINESCENT PROPERTIES; SCHIFF-BASE; FRAMEWORKS; NETWORKS; CHEMISTRY; TOPOLOGY; LIGAND; ACID; NETS;
D O I：
10.1016/j.molstruc.2013.04.004
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this paper, through the adjustment of alkyls attached to fluorene-based dicarboxylic acids, two Cd(II) coordination polymers featuring different entangled structures have been synthesized under the same solvothermal condition, which shows that the rational modulation of organic ligands' steric hindrance is an effective approach to the construction of novel entangled framework. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：116 / 120
页数：5
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