Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates

被引：6

作者：

Wang, Yiying ^{[1
]}

Shen, Hongtao ^{[2
]}

Qiu, Jianhua ^{[2
]}

Chen, Mengqi ^{[2
]}

Song, Weimin ^{[2
]}

Zhao, Mingqin ^{[1
]}

Wang, Longfei ^{[1
]}

Bai, Feng ^{[2
]}

Wang, Hongxia ^{[2
]}

Wu, Zhiyong ^{[1
]}

机构：

[1] Henan Agr Univ, Coll Tobacco Sci, Flavors & Fragrance Engn & Technol Res Ctr Henan, Zhengzhou, Peoples R China

[2] China Tobacco Henan Ind Co Ltd, Technol Ctr, Zhengzhou, Peoples R China

来源：

FRONTIERS IN CHEMISTRY | 2022年 / 10卷

关键词：

Hiyama cross-coupling; arylsilanes; thiuram reagents; C-S bond formation; aryl dithiocarbamates; CARBON BOND FORMATION; TRANSITION-METAL CATALYSIS; TETRAALKYLTHIURAM DISULFIDES; GRIGNARD-REAGENTS; S-ARYL; SELECTIVE SYNTHESIS; BORONIC ACIDS; PALLADIUM; DERIVATIVES; HALIDES;

D O I：

10.3389/fchem.2022.867806

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields.

引用

页数：11

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