Structural characterization of a mixed-ligand complex of copper(II) with 1,10-phenanthroline and the m-aminobenzoate ion

被引：7

作者：

Batool, S. S. ^{[1
]}

Gilani, S. R. ^{[1
]}

Tahir, M. N. ^{[2
]}

Harrison, W. T. A. ^{[3
]}

机构：

[1] Univ Engn & Technol, Dept Chem, Lahore, Pakistan

[2] Sargodha Univ, Dept Phys, Sargodha, Pakistan

[3] Univ Aberdeen, Dept Chem, Aberdeen, Scotland

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2016年 / 57卷 / 05期

关键词：

synthesis; copper(II); 1,10-phenanthroline; m-aminobenzoate ion; coordination polymer; CRYSTAL-STRUCTURE; ACID; PHENANTHROLINE; SUCCINATE;

D O I：

10.1134/S0022476616050206

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new copper(II) complex of 1,10-phenanthroline (C1(2)H(8)N(2)) and the meta-aminobenzoate ion (m-amb; C7H6NO (2) (-) ), having the formula Cu(C12H8N2)(C7H6NO2)Cla (TM) 0.5H(2)O, is prepared and characterized by elemental analysis, IR spectroscopy, and single crystal X-ray diffraction. The structure is built up from monomeric units in which the coordination environment around the metal ion is a square plane arising from a bidentate 1,10-phenanthroline molecule, a monodentate m-amb anion, and a chloride ion. A very long (Cu-N = 2.856(5) ) bond to the nitrogen atom of an adjacent m-amb ion generates [101] polymeric chains in the crystal. The crystal structure is consolidated by N-Ha (TM) a (TM) a (TM) O and O-Ha (TM) a (TM) a (TM) O hydrogen bonds and C-Ha (TM) a (TM) a (TM) O, C-Ha (TM) a (TM) a (TM) Cl, and aromatic pi-pi stacking interactions. Crystal data: C19H15ClCuN3O2.5, M (r) = 424.33, monoclinic, P2(1)/n (No. 14), a = 9.8200(5) , b = 10.9291(7) , c = 16.3803(9) , beta = 105.293(3)A degrees, V = 1695.74(17) (3), Z = 4, R(F) = 0.043, wR(F (2)) = 0.122.

引用

页码：991 / 996

页数：6

共 50 条

[1] Structural characterization of a mixed-ligand complex of copper(II) with 1,10-phenanthroline and the m-aminobenzoate ion
S. S. Batool
S. R. Gilani
M. N. Tahir
W. T. A. Harrison
[J]. Journal of Structural Chemistry, 2016, 57 : 991 - 996
[2] CRYSTAL-STRUCTURE OF A MIXED-LIGAND COMPLEX OF COPPER(II), 1,10-PHENANTHROLINE, AND GLYCYLGLYCINE DIANION - GLYCYLGLYCINATO(1,10-PHENANTHROLINE)COPPER(II) TRIHYDRATE
LIM, MC
SINN, E
MARTIN, RB
[J]. INORGANIC CHEMISTRY, 1976, 15 (04) : 807 - 811
[3] Mixed-ligand complexes of copper(II) and α-hydroxycarboxylic acids and 1,10-phenanthroline
Carballo, R
Covelo, B
Balboa, S
Castiñeiras, A
Niclós, J
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2001, 627 (05): : 948 - 954
[4] ISOMERISM OF MIXED-LIGAND COPPER(II) COMPLEXES CONTAINING 1,10-PHENANTHROLINE AND OXALATE
OBRIEN, P
STAFFORD, C
YOUNG, LC
[J]. INORGANICA CHIMICA ACTA, 1988, 147 (01) : 3 - 4
[5] Mixed-ligand copper(II) complexes with ascorbic and nicotinic acids and 1,10-phenanthroline
Korotchenko, NM
Dobarkina, VA
Skorik, NA
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2005, 50 (11) : 1804 - 1809
[6] A new mixed-ligand copper(II) complex containing azide and 1,10-phenanthroline: Crystal structure and properties
Liang, M
Wang, WZ
Liu, ZQ
Liao, DZ
Jiang, ZH
Yan, SP
Cheng, P
[J]. JOURNAL OF COORDINATION CHEMISTRY, 2003, 56 (17) : 1473 - 1480
[7] The Volatile Mixed-Ligand Lanthanum(III) Complex with Acetylacetone and 1,10-Phenanthroline
Kuz'mina, N. P.
Chugarov, N. V.
Pisarevskii, A. P.
Martynenko, L. I.
[J]. Russian Journal of Coordination Chemistry, 23 (06):
[8] Volatile mixed-ligand lanthanum(III) complex with acetylacetone and 1,10-phenanthroline
Kuz'mina, N.P.
Chugarov, N.V.
Pisarevskij, A.P.
Martynenko, L.I.
[J]. Koordinatsionnaya Khimiya, 23 (06): : 450 - 455
[9] The Volatile Mixed-Ligand Lanthanum(III) Complex with Acetylacetone and 1,10-Phenanthroline
Kuz'mina, N. P.
Chugarov, N. V.
Pisarevskii, A. P.
Martynenko, L. I.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1997, 23 (06) : 417 - 421
[10] SYNTHESES AND STRUCTURES OF 5 AND 6 COORDINATE MIXED-LIGAND COMPLEXES OF COPPER(II) WITH 1,10-PHENANTHROLINE
GREINER, GT
PARKER, OJ
BRENEMAN, GL
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 205 : 603 - INOR

← 1 2 3 4 5 →