Cooling dynamics of photo-excited negative carbon cluster ions stored in an ion storage ring

被引:6
|
作者
Furukawa, T. [1 ]
Ito, G. [1 ]
Goto, M. [2 ]
Majima, T. [1 ]
Tanuma, H. [1 ]
Matsumoto, J. [3 ]
Shiromaru, H. [3 ]
Hansen, K. [4 ]
Azuma, T. [1 ,2 ]
机构
[1] Tokyo Metropolitan Univ, Dept Phys, Hachioji, Tokyo 1920397, Japan
[2] RIKEN, Atom Mol & Opt Phys Lab, Wako, Saitama 3510198, Japan
[3] Tokyo Metropolitan Univ, Dept Chem, Hachioji, Tokyo 1920397, Japan
[4] Univ Gothenburg, Dept Phys, S-41296 Gothenburg, Sweden
关键词
Carbon cluster anion; Radiative cooling; Depletion cooling; Inverse internal conversion; Recurrent fluorescence; THERMIONIC EMISSION; SPECTRA; SPECTROSCOPY; ANIONS;
D O I
10.1016/j.nimb.2014.12.016
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
A newly found fast radiative cooling process of C-6(-) is studied by simulation based on statistical sharing of the internal energy by the vibrational modes both in the electronic ground and excited states. For comparison, a contrasting slow cooling of C6H- is simulated by the same procedure. The simulation demonstrates a distinct difference in the time evolution of energy distributions between C-6(-) and C6H-, and well reproduces the observed fast cooling of C-6(-) by recurrent electronic transitions and the slow cooling of C6H- by vibrational de-excitation. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:192 / 196
页数:5
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