Comment on "Synthesis, growth and characterization of a new metal organic NLO material: Dibromo bis (L-proline) Cd(II)" [J. Mol. Struct. 1080 (2015) 37-43]

被引:4
|
作者
Srinivasan, Bikshandarkoil R. [1 ]
Naik, Madhavi Z. [1 ]
Narvekar, Kedar U. [1 ]
机构
[1] Goa Univ, Dept Chem, Bambolim 403206, Goa, India
关键词
Dibromobis(L-proline)Cadmium(II); Crystal structure; Dibromobis(L-proline)zinc(II); Diiodobis(2-aminopyridine)cadmium(II); Soft magnet; Diamagnetic; SINGLE-CRYSTAL;
D O I
10.1016/j.molstruc.2015.06.042
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The title paper by Boopathi and Ramasamy reports a study on the crystal growth and characterization of dibromobis(L-proline)cadmium(II) 1. Many points of criticism, concerning the crystal structure of 1 and the magnetic properties of 1, dibromobis(L-proline)zinc(II) 2 (J. Mol. Struc. 1033 (2013) 121-126) and diiodobis(2-aminopyridine)cadmium(II) 3 (J. Mol. Struc. 1042 (2013) 25-31) are described to show that compounds 1 to 3 are not soft magnets but instead diamagnetic solids. (C) 2015 Elsevier B.V. All rights reserved.
引用
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页码:16 / 17
页数:2
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