THE ELECTROCHEMICAL BEHAVIOUR OF CHALCOPYRITE IN SULFURIC ACID IN THE PRESENCE OF CYSTEINE

被引:0
|
作者
Maluckov, Biljana S. [1 ]
Dimitrijevic, Mile [1 ]
Kovacevic, Renata [2 ]
Mladenovic, Srba [1 ]
机构
[1] Univ Belgrade, Tech Fac Bor, Vojske Jugoslavije 12, Bor 19210, Serbia
[2] Min & Met Inst Bor, Zeleni Bulevar 35, Bor 19210, Serbia
关键词
electrochemistry; chalcopyrite; cysteine; ALKALINE SULFATE-SOLUTIONS; AMINO-ACIDS; CORROSION-INHIBITORS; ANODIC-DISSOLUTION; COPPER; STEEL; IRON; SURFACE; BORNITE; IONS;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this paper the effects of different concentrations of cysteine in 10(-2) mol L-1 H2SO4 on dissolution of chalcopyrite are studied. The cyclic voltammograms at the scan rate values of 1 mV s(-1), 5 mV s(-1), 10 mV s(-1) and 20 mV s(-1) are observed. After cyclic voltammetry, the analysis of dissolved metals and sulfur in the solutions was done. The results show that the highest concentrations of the Fe and Cu are obtained at the scan rate 1 mV s(-1). With increasing scan rate only fast reactions can be realized. The low scan rates are associated with slow reactions. Therefore, a molar ratio of Cu/Fe is the largest at the scan rate of 1mV s-1 and concentration of 10(-2) mol L-1 Cys.
引用
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页码:809 / 814
页数:6
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