Ionic liquids in dispersive liquid-liquid microextraction

被引:233
|
作者
Trujillo-Rodriguez, Maria J. [1 ]
Rocio-Bautista, Priscilla [1 ]
Pino, Veronica [1 ]
Afonso, Ana M. [1 ]
机构
[1] Univ La Laguna, Dept Quim Analit Nutr & Bromatol, San Cristobal la Laguna 38206, Tenerife, Spain
关键词
Dispersive liquid-liquid microextraction; Ionic liquid; Metal; Microwave-assisted; Organic compound; Organic solvent; Preconcentration; Surfactant; Ultrasound-assisted; Vortex-assisted; ATOMIC-ABSORPTION-SPECTROMETRY; COLD-INDUCED AGGREGATION; ENVIRONMENTAL WATER SAMPLES; POLYCYCLIC AROMATIC-HYDROCARBONS; SOLID-PHASE MICROEXTRACTION; SENSITIVE DETERMINATION; ORGANIC-COMPOUNDS; TRACE DETERMINATION; ORGANOPHOSPHORUS PESTICIDES; PRECONCENTRATION METHOD;
D O I
10.1016/j.trac.2013.06.008
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this review, we summarize the most recent analytical developments aimed at employing Ionic liquids (ILs) in dispersive liquid-liquid microextraction (DLLME). Four main operation modes can be distinguished: (1) conventional IL-DLLME; (2) temperature-controlled IL-DLLME; (3a) ultrasound-assisted, (3b) microwave-assisted or (3c) vortex-assisted IL-DLLME; and, (4) in-situ IL-DLLME. In these modes, the dispersive solvent can be an organic solvent, a surfactant, or a hydrophilic IL. In some cases, a dispersive solvent is not even necessary. We discuss practical applications of IL-DLLME to determine metals and organic compounds in a variety of samples. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:87 / 106
页数:20
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