A new rhodamine derivative-based chemosensor for highly selective and sensitive determination of Cu2+

被引:75
|
作者
Puangploy, Premsak [1 ]
Smanmoo, Srung [2 ]
Surareungchai, Werasak [1 ,3 ]
机构
[1] King Mongkuts Univ Technol Thonburi, Sch Bioresources & Technol, Bangkok 10150, Thailand
[2] Natl Ctr Genet Engn & Biotechnol BIOTEC, Bioresources Res Unit, KlongLuang 12120, Pathumthani, Thailand
[3] King Mongkuts Univ Technol Thonburi, Biol Engn Program, Bangkok 10150, Thailand
关键词
Chemosensor; Copper (II) ion; Pyrrole; Rhodamine derivative; Turn-on fluorescence; ON FLUORESCENT CHEMOSENSOR; OFF-ON; STRIPPING VOLTAMMETRY; COPPER; SENSOR; CU(II); PROBE; CADMIUM; ION;
D O I
10.1016/j.snb.2013.12.037
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A new rhodamine derivative (R1) has been synthesized by a hydrazone formation of rhodamine B hydrazide with pyrrole-2-carboxaldehyde and its binding affinity to metal ions were examined. R1 shows highly binding selectivity to Cu2+ over commonly coexistent metal ions in neutral aqueous-organic media including alkali, alkaline-earth and transition metals. The linear response to Cu2+ was obtained across the concentration range of 0.4-10 mu M with the detection limit of 280 nM. Using newly synthesized probe R1, determination of Cu2+ concentration in drinking water and serums, and living cell imaging of Cu2+ were carried out. Also, by incorporating the R1 with filter paper, the sensor was performed in Cu2+ spiked samples. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:679 / 686
页数:8
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