Effect of self-assembled surfactant structures on ion transport across the liquid|liquid interface

被引：25
|
作者：
Strutwolf, J
Manzanares, JA [1 ]
Williams, DE
机构：
[1] Univ Valencia, Dept Thermodynam, E-46100 Burjassot, Spain
[2] UCL, Dept Chem, London WC1 0AJ, England
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 1999年 / 1卷 / 3-4期
关键词：
ITIES; ion transfer; self-assembled monolayers; surfactants; double-layer effects;
D O I：
10.1016/S1388-2481(99)00025-9
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
In this paper, the effect of a coadsorbed polyanion-cationic surfactant system on the transport of tetraethylammonium ion across the water / 1,2-dichloroethane interface is studied. It is shown that the change in double-layer structure due to the presence of adsorbed or coadsorbed surfactant can explain the experimental observations, thus concluding that no other effects on ion transfer (e.g., steric hindrance) are relevant under these experimental conditions. The implications of these results are discussed. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：139 / 144
页数：6
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