Direct electrochemical synthesis of novel transition metal chelates of tridentate azomethinic ligands

被引：12
|
作者：
Kharisov, BI
Garnovskii, DA
Blanco, LM
Burlov, AS
Vasilchenko, IS
Garnovskii, AD
机构：
[1] Univ Autonoma Nuevo Leon, Fac Ciencias Quim, Mexico City 66450, DF, Mexico
[2] Rostov State Univ, Inst Phys & Organ Chem, Rostov On Don 344006, Russia
来源：
POLYHEDRON | 1999年 / 18卷 / 07期
关键词：
electrosynthesis; azomethinic ligands; mononuclear chelates;
D O I：
10.1016/S0277-5387(98)00383-0
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New chelates of the type ML(L-1)(n). MeOH (n = 1, 2) were obtained on the basis of the tridentate azomethinic ligands 2-N-tosylamine(2'-hydroxybenzal)aniline (L) and 2-N-tosylamine(2'-tosylaminobenzal)aniline (L-1) and zero-valent transition metals (Co, Ni, Cu, Zn, Cd) under electrosynthesis conditions. The mononuclear character of these products and the participation of N2O- or N-3 groups of the azomethinic Ligands in the coordination are demonstrated by IR, H-1 NMR spectral and magnetic data (77-293 K). (C) 1999 Elsevier Science Ltd, All rights reserved.
引用
收藏
页码：985 / 988
页数：4
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