Sono-assembly of nanostructures via tyrosine-tyrosine coupling reactions at the interface of acoustic cavitation bubbles

被引:30
|
作者
Cavalieri, Francesca [1 ,2 ]
Colombo, Enrico [3 ]
Nicolai, Eleonora [4 ]
Rosato, Nicola [4 ]
Ashokkumar, Muthupandian [3 ]
机构
[1] Univ Melbourne, Dept Chem & Biomol Engn, Melbourne, Vic 3010, Australia
[2] Univ Roma Tor Vergata, Dipartimento Sci & Tecnol Chim, Via Ric Sci 1, I-00173 Rome, Italy
[3] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia
[4] Univ Roma Tor Vergata, Dept Expt Med & Surg, Via Montpellier 1, I-00133 Rome, Italy
关键词
POLYPHENOLIC COMPOUNDS; GREEN TEA; OXIDATION; ULTRASOUND; PRODUCTS; POLYMERIZATION; INGREDIENTS; COMPLEXES; PEPTIDES; RADICALS;
D O I
10.1039/c6mh00250a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This work demonstrates that the reactive and oscillating surface of acoustic cavitation microbubbles acts as a catalytic binding site for the coupling of amphiphilic biomolecules bearing tyrosine moieties at the gas-liquid interface. We show a one-step, controlled ultrasonic process to self assemble tyrosine moieties into highly fluorescent uniformly sized sub-micron particles with new optical and functional properties.
引用
收藏
页码:563 / 567
页数:5
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