Sr-Nd-Hf-Pb isotope geochemistry, of basaltic rocks from the Cretaceous Gyeongsang Basin, South Korea: Implications for basin formation

To better understand the formative mechanism of the Cretaceous Gyeongsang Basin in South Korea, we determined the geochemical compositions of Early Cretaceous syntectonic basaltic rocks intercalated with basin sedimentary assemblages. Two distinct compositional groups appeared: tholeiitic to calc-alkaline basalts from the Yeongyang sub-basin and high-K to shoshonitic basaltic trachyandesites from the Jinju and Uiseong sub-basins. All collected samples exhibit patterns of light rare earth element enrichment and chondrite-normalized (La/Yb)(N) ratios ranging from 2.4 to 23.6. In a primitive-mantle-normalized spidergram, the samples show distinctive negative anomalies in Nb, Ta, and Ti and a positive anomaly in Pb. The basalts exhibit no or a weak positive U anomaly in a spidergram, but the basaltic trachyandesites show a negative U anomaly. The basalts have highly radiogenic Sr [(Sr-87/Sr-86)(i) = 0.70722-0.71145], slightly negative epsilon(Nd), positive epsilon(Hf) [(epsilon Nd)(t) = -2.7 to 0.0; (epsilon(Hf)); = +2.9 to +6.4], and radiogenic Pb isotopic compositions [((206)pb/(204)pb)(i) = 18.20-19.19; ((207)pb/Pb-204)(i) = 15.60-15.77; (Pb-208/Pb-204)(i) = 38.38-39.11]. The basaltic trachyandesites are characterized by radiogenic Sr [(Sr-87/Sr-86)(i) = 0.70576-0.71119] and unradiogenic Nd, Hf, and Pb isotopic compositions [(epsilon(Nd))(i) = -14.0 to -1.4; (epsilon(Hf)) = -17.9 to +3.7; (Pb-206/Pb-204) = 17.83-18.25; ((207)pb/Pb-204)(i) = 15.57-15.63; Sr (Pb-208/Pb-204)(i) = 38.20-38.7 The "crust-like" signatures, such as negative Nb-Ta anomalies, elevated Sr isotopic compositions, and negative epsilon(Nd)(t) and epsilon(Hf)(t) values, of the basaltic trachyandesites resemble the geochemistry of Early Cretaceous mafic volcanic rocks from the southern portion of the eastern North China Craton. Considering the lower-crust-like low U/Pb and high Th/U ratios and the unradiogenic Pb isotopic compositions, the basaltic trachyandesites are considered to be derived from lithospheric mantle modified by interaction with melts that originated from foundered eclogite. Basaltic volcanism in the Yeongyang sub-basin is coeval with the basaltic trachyandesite magmatism, but it exhibits an elevated Sr-87/Sr-86 ratio at a given Nd-143/Nd-144 and highly radiogenic Pb isotopic compositions, which imply an origin from an enriched but heterogeneous lithospheric mantle source. Melts from subducted altered oceanic basalt and pelagic sediments are considered to be the most likely source for the metasomatism. An extensional tectonic regime induced by highly oblique subduction of the Izanagi Plate beneath the eastern Asian margin during the Early Cretaceous might have triggered the opening of the Gyeongsang Basin. Lithospheric thinning and the resultant thermal effect of asthenospheric upwelling could have caused melting of the metasomatized lithospheric mantle, producing the Early Cretaceous basaltic volcanism in the Gyeongsang Basin. (C) 2013 Elsevier Ltd. All rights reserved.