Pd-catalyzed oxidative acylation of 2-phenoxypyridines with alcohols via C-H bond activation

被引：35
|
作者：
Kim, Minyoung [1 ]
Sharma, Satyasheel [1 ]
Park, Jihye [1 ]
Kim, Mirim [1 ]
Choi, Yeonhee [1 ]
Jeon, Yukyoung [1 ]
Kwak, Jong Hwan [1 ]
Kim, In Su [1 ]
机构：
[1] Sungkyunkwan Univ, Sch Pharm, Suwon 440746, South Korea
来源：
TETRAHEDRON | 2013年 / 69卷 / 32期
关键词：
Acylation; Alcohols; C-H activation; Palladium; 2-Phenoxypyridines; ALPHA-OXOCARBOXYLIC ACIDS; TERT-BUTYL HYDROPEROXIDE; CARBON-HYDROGEN BONDS; O-METHYL OXIMES; ROOM-TEMPERATURE; DECARBOXYLATIVE ACYLATION; ALDEHYDES; ACETANILIDES; ACYLPHLOROGLUCINOLS; FUNCTIONALIZATION;
D O I：
10.1016/j.tet.2013.06.008
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A palladium-catalyzed oxidative acylation of 2-phenoxypyridines with benzylic and aliphatic alcohols via C-H bond activation is described. This protocol represents direct access to biologically active ortho-acylphenol derivatives, and provides new opportunities to use readily available alcohols as starting materials for catalytic acylation reactions. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6552 / 6559
页数：8
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