Phase Evolution and Superconducting Properties of Boron-doped (Bi,Pb)-2223 HTSs

Two series of the nominally pure (control) and boron-doped (Bi,Pb)-2223 HTSs with composition Bi1.7Pb0.3Ca2Sr2Cu3BxOy (x=0, 0.05, 0.5, 1.5) were prepared under the different conditions: in an alumina crucibles and on an alumina plates. The influence of boron-doping as well as annealing conditions on the high-T-c 2223 phase evolution was studied using X-ray diffraction (XRD), resistivity and AC susceptibility measurements. Obtained results indicate that boron dopant drastically accelerates the formation of (Bi,Pb)-2223 HTS synthesized in an alumina crucibles. The boron-doped sample with x=0.5 revealed significant improvement in the T-c compared to the control sample (from 72K up to 100K). On the other hand, the additives of boron (x=0.05 and 0.5) have shown to have a beneficial effect on the formation of (Bi,Pb)-2223 HTSs prepared by the heat treatment of precursors on alumina plates, although do not essentially affect the critical temperature T-c=102 K of nominally pure compound.