Selective oxidation of cyclohexane with hydrogen peroxide in the presence of copper pyrophosphate

被引：35
|
作者：
Du, Ying [1 ,2 ]
Xiong, Yonglian [1 ]
Li, Jing [1 ]
Yang, Xiangguang [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, Lab Green Chem & Proc, Changchun 130022, Peoples R China
[2] Chinese Acad Sci, Grad Sch, Changchun 130022, Peoples R China
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2009年 / 298卷 / 1-2期
关键词：
Copper pyrophosphate; Cyclohexane; Hydrophobicity; Selective oxidation; CU(II) COMPLEXES; SYSTEM HYDROGEN; ACETIC-ACID; CATALYST; ZEOLITE; SOLVENT; ACETONITRILE; OXIDANT; ALKANES; OXYGEN;
D O I：
10.1016/j.molcata.2008.09.020
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Liquid phase oxidation of cyclohexane was carried out under mild reaction condition over copper pyrophosphate catalyst in CH3CN using hydrogen peroxide as an oxidant at the temperature between 25 and 80 degrees C. The copper pyrophosphate catalyst was characterized by means of XRD, FT-IR and water contact angle measurement. It was found that appropriate surface hydrophobicity is the key factor for the excellent performance of the catalyst. In addition, a significant improvement for the cyclohexane conversion in the presence of organic acid was observed. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：12 / 16
页数：5
相关论文
共 50 条
  • [31] Kinetics and Mechanism of the Reaction of Coherently Synchronized Oxidation and Dehydrogenation of Cyclohexane by Hydrogen Peroxide
    Aghamammadova, S.
    Nagieva, I.
    Gasanova, L.
    Nagiev, T.
    2016 6TH INTERNATIONAL CONFERENCE ON CHEMISTRY AND CHEMICAL PROCESS (ICCCP 2016), 2016, 49
  • [32] Oxidation of cyclohexane with hydrogen peroxide over β-zeolites with various Si/Al ratios
    Ohno, Ryohei
    Taniya, Keita
    Tsuruya, Shigeru
    Ichihashi, Yuichi
    Nishiyama, Satoru
    CATALYSIS TODAY, 2013, 203 : 60 - 65
  • [33] CATALYSIS OF THE OXIDATION OF CYCLOHEXANE AND THE DECOMPOSITION OF HYDROGEN-PEROXIDE BY HETEROPOLY-COMPLEXES
    KUZNETSOVA, NI
    DETUSHEVA, LG
    KUZNETSOVA, LI
    FEDOTOV, MA
    LIKHOLOBOV, VA
    KINETICS AND CATALYSIS, 1992, 33 (03) : 415 - 421
  • [34] A highly efficient oxidation of cyclohexane over VPO catalysts using hydrogen peroxide
    Pillai, UR
    Sahle-Demessie, E
    CHEMICAL COMMUNICATIONS, 2002, (18) : 2142 - 2143
  • [35] Influence of compressed carbon dioxide on the oxidation of cyclohexane with hydrogen peroxide in acetic acid
    Gao, L
    Jiang, T
    Han, BX
    Zong, BN
    Zhang, XX
    Zhang, JC
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2006, 59 (03) : 225 - 228
  • [36] OXIDATION OF CYCLOHEXANE BY HYDROGEN-PEROXIDE CATALYZED BY V5+ IONS
    GEKHMAN, AE
    SHISHKIN, DI
    MOISEEV, II
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1987, 36 (06): : 1330 - 1330
  • [37] Catalytic oxidation of cyclohexane with hydrogen peroxide and a tetracopper(II) complex in an ionic liquid
    Ribeiro, Ana P. C.
    Martins, Luisa M. D. R. S.
    Hazra, Susanta
    Pombeiro, Armando J. L.
    COMPTES RENDUS CHIMIE, 2015, 18 (07) : 758 - 765
  • [38] Removal of cyanide in aqueous solution by oxidation with hydrogen peroxide in presence of copper-impregnated activated carbon
    Yeddou, Ahmed Reda
    Chergui, Salima
    Chergui, Abdelmalek
    Halet, Farid
    Hamza, Amaouche
    Nadjemi, Boubekeur
    Ould-Dris, Aissa
    Belkouch, Jamal
    MINERALS ENGINEERING, 2011, 24 (08) : 788 - 793
  • [39] Copper(I) and copper(II) metallacycles as catalysts for microwave assisted selective oxidation of cyclohexane
    Galassi, Rossana
    Simon, Oumarou Camille
    Burini, Alfredo
    Tosi, Giorgio
    Conti, Carla
    Graff, Claudia
    Martins, Nuno M. R.
    Guedes da Silva, M. Fatima C.
    Pombeiro, Armando J. L.
    Martins, Luisa M. D. R. S.
    POLYHEDRON, 2017, 134 : 143 - 152
  • [40] Preparation of amorphous copper - chromium oxides catalysts for selective oxidation of cyclohexane
    Sun, Lei
    Liu, Junhua
    Luo, Wei
    Yang, Yue
    Wang, Fang
    Weerakkody, Chandima
    Suib, Steven L.
    MOLECULAR CATALYSIS, 2018, 460 : 16 - 26
12345