Recyclable hydrotalcite clay catalysed Baylis-Hillman reaction

被引:18
|
作者
Srivastava, Vivek [1 ]
机构
[1] NIIT Univ, Neemrana 301705, India
关键词
Baylis-Hillman reaction; hydrotalcite clay; ionic liquid; heterogeneous catalysis; lactone ceramide analogue; MG-AL HYDROTALCITE; IONIC LIQUIDS; REUSABLE CATALYST; ALDOL; KNOEVENAGEL; EFFICIENT; PROLINE; BASE; ALDEHYDES; SYSTEM;
D O I
10.1007/s12039-013-0472-0
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Baylis-Hillman reaction using ionic liquid/hydrotalcite clay catalytic system has been observed to be more reactive in terms of yield and reaction rate than DABCO/acetonitrile system. During the process, the reactants enjoy ionic liquid/hydrotalcite clay catalytic system and gives corresponding Baylis-Hillman reaction products in good yield. The application of our catalytic system has been diversifying for the synthesis of lactone ceramide analogue from (S)-Garner aldehyde-methyl acrylate using Baylis-Hillman reaction. Recycling of ionic liquid/hydrotalcite clay catalytic system has also been demonstrated in this report.
引用
收藏
页码:1207 / 1212
页数:6
相关论文
共 50 条
  • [1] Recyclable hydrotalcite clay catalysed Baylis–Hillman reaction
    VIVEK SRIVASTAVA
    Journal of Chemical Sciences, 2013, 125 : 1207 - 1212
  • [2] Ionic liquids as a recyclable reaction medium for the Baylis-Hillman reaction
    Rosa, JN
    Afonso, CAM
    Santos, AG
    TETRAHEDRON, 2001, 57 (19) : 4189 - 4193
  • [3] An intramolecular Baylis-Hillman reaction catalysed by secondary amines
    Black, GP
    Dinon, F
    Fratucello, S
    Murphy, PJ
    Nielsen, M
    Williams, HL
    TETRAHEDRON LETTERS, 1997, 38 (49) : 8561 - 8564
  • [4] Baylis-Hillman reaction and chemical transformations of Baylis-Hillman adducts
    Lee, KY
    Gowrisankar, S
    Kim, JN
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (10): : 1481 - 1490
  • [5] N-methylprolinol catalysed asymmetric Baylis-Hillman reaction
    Krishna, PR
    Kannan, V
    Reddy, PVN
    ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (06) : 603 - 606
  • [6] Baylis-Hillman reaction of isatin derivatives: Isatins as a new entry for the Baylis-Hillman reaction
    Chung, YM
    Im, YJ
    Kim, JN
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2002, 23 (11) : 1651 - 1654
  • [7] The asymmetric Baylis-Hillman reaction
    Brzezinski, LJ
    Rafel, S
    Leahy, JW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (18) : 4317 - 4318
  • [8] Mechanochemistry and the Baylis-Hillman reaction
    Hesse, Andrew J.
    Mack, James
    Shumba, Maxwell
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 758 - 758
  • [9] Diastereoselective Baylis-Hillman reaction
    Chen, K
    Pan, JF
    Lee, WD
    Yang, KS
    Wang, SG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U182 - U182
  • [10] AN INTRAMOLECULAR BAYLIS-HILLMAN REACTION
    ROTH, F
    GYGAX, P
    FRATER, G
    TETRAHEDRON LETTERS, 1992, 33 (08) : 1045 - 1048