A review on the progress of the photocatalytic removal of refractory pollutants from water by BiOBr-based nanocomposites

Organic matters from various sources such as the manufacturing, agricultural, and pharmaceuticals industries is continuously discharged into water bodies, leading to increasingly serious water pollution. Photocatalytic technology is a clean and green advanced oxidation process, that can successfully decompose various organic pollutants into small inorganic molecules such as carbon dioxide and water under visible light irradiation. Bismuth oxybromide (BiOBr) is an attractive visible light photocatalyst with good photocatalytic performance, suitable forbidden band-width, and a unique layered structure. However, the rapid combination of the electron-hole pairs generated in BiOBr leads to low photocatalytic activity, which limits its photocatalytic performance. Due to its unique electronic structure, BiOBr can be coupled with a variety of different functional materials to improve its photocatalytic performance. In this paper, We present the morphologically controllable BiOBr and its preparation process with the influence of raw materials, additives, solvents, synthesis methods, and synthesis conditions. Based on this, we propose design synthesis considerations for BiOBr-based nanocomplexes in four aspects: structure, morphology and crystalline phase, reduction of electron-hole pair complexation, photocorrosion resistance, and scale-up synthesis. The literature on BiOBr-based nanocomposites in the last 10 years (2012-2022) are summarized into seven categories, and the mechanism of enhanced photocatalytic activity of BiOBr-based nanocomposites is reviewed. Moreover, the applications of BiOBr-based nanocomposites in the fields of degradation of dye wastewater, antibiotic wastewater, pesticide wastewater, and phenol-containing wastewater are reviewed. Finally, the current challenges and prospects of BiOBr-based nanocomposites are briefly described. In general, this paper reviews the construction of BiOBr-based nano -composites, the mechanism of photocatalytic activity enhancement and its research status and application prospects in the degradation of organic pollutants.