Lean NOx Trap Chemistry Under Lean-Gasoline Exhaust Conditions: Impact of High NOx Concentrations and High Temperature

The primary technical barrier to deployment of fuel saving lean gasoline engines is NOx emissions control. We conducted automated flow reactor experiments on a commercial LNT catalyst to identify opportunities and challenges associated with the higher temperatures and higher NOx concentrations expected in lean gasoline applications. Overall NOx conversion was quite high at low to moderate temperatures, but dropped off at high temperatures. The decrease in NOx conversion with temperature was worse for higher inlet NOx concentrations. As expected from equilibrium considerations, the catalyst stored more NOx under higher gas phase NOx concentrations, but that NOx was rapidly released during the rich phase and slipped out of the catalyst before it could be converted to N-2 by incoming reductant. This rich phase NOx release was the primary factor limiting performance of the catalyst at high temperatures, and resulted in significant spikes of NOx that would likely exceed any not-to-exceed regulated emissions levels. N2O production was also significant, and increased with NOx concentration. The catalyst made very little NH3 at high temperatures. NH3 yield was significant at the lowest operating temperature studied, but it decreased with increasing NOx concentration.