Optimization of the catalytic wet peroxide oxidation of phenol over the Fe/NH4Y catalyst

被引:1
|
作者
Xu Junqiang [1 ]
Guo Fang [1 ]
Zou Shushu [1 ]
Quan Xuejun [1 ]
机构
[1] Chongqing Univ Technol, Sch Chem & Chem Engn, Chongqing 400050, Peoples R China
来源
关键词
zeolite; NH4Y; phenol; wastewater treatment; WASTE-WATER; BED REACTOR; DEGRADATION;
D O I
10.4028/www.scientific.net/MSF.694.640
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The heterogeneous NH4Y zeolite-supported iron catalysts were prepared by incipient wetness impregnation. The catalysis oxidation degradation of phenol was carried over the heterogeneous catalyst in the peroxide catalytic oxidation process. Compared with the homogeneous Fenton process, the Fe/NH4Y-acid catalyst can effectively degrade contaminants with high catalytic activity and easy catalyst separation from the solution. The phenol removal efficiency could reach 96% in the optimum experimental conditions. These process conditions were as follows: iron content is 5%, reaction time was 60 min, reaction temperature was 70 degrees C, the catalyst dosage was 1g/L, the H2O2 concentration was 1.65g/L.
引用
收藏
页码:640 / 644
页数:5
相关论文
共 50 条
  • [1] CATALYTIC HYDRODESULFURIZATION OF DIBENZOTHIOPHENE OVER NH4Y ZEOLITE CATALYST
    NAGAI, M
    URIMOTO, H
    SAKIKAWA, N
    [J]. NIPPON KAGAKU KAISHI, 1975, (02) : 356 - 361
  • [2] Catalytic wet peroxide oxidation of phenol with a Fe/active carbon catalyst
    Zazo, J. A.
    Casas, J. A.
    Mohedano, A. F.
    Rodriguez, J. J.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 65 (3-4) : 261 - 268
  • [3] Catalytic wet oxidation of phenol by hydrogen peroxide over pillared clay catalyst
    Guo, J
    Al-Dahhan, M
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (12) : 2450 - 2460
  • [4] Phenol Degradation by Catalytic Wet Hydrogen Peroxide Oxidation on Fe/Active Carbon Catalyst
    Yang Yingchun
    Lu Yuangang
    Ye Zhixiang
    He Liping
    Yu Jing
    [J]. MATERIALS SCIENCE AND INFORMATION TECHNOLOGY, PTS 1-8, 2012, 433-440 : 147 - 152
  • [5] Catalytic wet oxidation of bisphenol A with hydrogen peroxide over Fe/AC catalyst
    Zhou, Wen
    Cheng, Zhiliang
    Quan, Xuejun
    Chen, Bo
    [J]. Huagong Xuebao/CIESC Journal, 2013, 64 (03): : 936 - 942
  • [6] Catalytic wet peroxide oxidation of phenol over Fe-exchanged pillared beidellite
    Catrinescu, C
    Teodosiu, C
    Macoveanu, M
    Miehe-Brendlé, J
    Le Dred, R
    [J]. WATER RESEARCH, 2003, 37 (05) : 1154 - 1160
  • [7] Efficient catalytic wet peroxide oxidation of phenol over Fe-ZSM-5 catalyst in a fixed bed reactor
    Yan, Ying
    Jiang, Songshan
    Zhang, Huiping
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2014, 133 : 365 - 374
  • [8] Copper hydroxyl sulfate as a heterogeneous catalyst for the catalytic wet peroxide oxidation of phenol
    Huang, Kai
    Wang, Jiejie
    Wu, Dongfang
    Lin, Sheng
    [J]. RSC ADVANCES, 2015, 5 (11): : 8455 - 8462
  • [9] Catalytic wet peroxide oxidation of phenol solution over Fe–Mn binary oxides diatomite composite
    Bui Hai Dang Son
    Vo Quang Mai
    Dang Xuan Du
    Nguyen Hai Phong
    Nguyen Duc Cuong
    Dinh Quang Khieu
    [J]. Journal of Porous Materials, 2017, 24 : 601 - 611
  • [10] Investigation of the catalytic wet peroxide oxidation of phenol over different types of Cu/ZSM-5 catalyst
    Valkaj, K. Maduna
    Katovic, A.
    Zrncevic, S.
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2007, 144 (03) : 663 - 667