Bis(2,2′-bipyridine-κ2N,N′)dichloridoplatinum(IV) dichloride monohydrate

被引：4
|
作者：
Kim, Nam-Ho [1 ]
Hwang, In-Chul [2 ]
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Res Inst Catalysis, Sch Appl Chem Engn, Kwangju 500757, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809000725
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [PtCl2(C10H8N2)(2)]Cl-2 center dot H2O, the Pt4+ ion is six- coordinated in a distorted octahedral environment by four N atoms from the two 2,2 '-bipyridine ligands and two Cl atoms. As a result of the different trans influences of the N and Cl atoms, the Pt-N bonds trans to the Cl atom are slightly longer than those trans to the N atom. The compound displays intermolecular hydrogen bonding between the water molecule and the Cl anions. There are intermolecular pi-pi interactions between adjacent pyridine rings, with a centroid-centroid distance of 3.962 angstrom.
引用
收藏
页码：M180 / U600
页数：10
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