Molecular interactions during adsorption and micellization in ionic surfactant solutions: 1. Adsorption kinetics of ionic surfactants

被引：0
|
作者：
Makarevich, NA [1 ]
Dikhtievskaya, LV [1 ]
机构：
[1] Natl Acad Sci Belarus, Inst Gen & Inorgan Chem, Minsk 220072, BELARUS
来源：
COLLOID JOURNAL | 1999年 / 61卷 / 03期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The effect of the binding of counterions with the adsorption complexes of ionic surfactants on the adsorption isotherms was considered, and the modified Hill-de Beer and Fowler adsorption isotherms were obtained. The dynamic surface tension of aqueous solutions of cationic surfactants (hydrochlorides of amines with a hydrocarbon chain length of C-12-C-18) was determined by the Wilhelmy plate method, and the diffusion coefficients were calculated taking into account deviation of the adsorption system from the ideal behavior. Contributions from the lateral long-range interactions of the surfactants, the diffusion barrier, and the electrostatic interaction of surfactant ions to the energetics of a process were estimated.
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页码：320 / 326
页数：7
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