One three-dimensional Gd(III) coordination polymer with 1,2-phenylenediacetate exhibiting ferromagnetic interaction and large magnetocaloric effect

被引：9

作者：

Li, Zhong-Yi ^{[1
]}

Li, Jing-Yu ^{[2
]}

Pei, Lian-Lian ^{[1
]}

Zhang, Xiang-Fei ^{[1
]}

Cao, Guang-Xiu ^{[1
]}

Zhang, Chi ^{[1
]}

Li, Su-Zhi ^{[1
]}

Zhai, Bin ^{[1
]}

机构：

[1] Shangqiu Normal Univ, Coll Chem & Chem Engn, Engn Res Ctr Photoelect Funct Mat, Henan Key Lab Biomol Recognit & Sensing, Shangqiu 476000, Peoples R China

[2] Zhengzhou Univ Aeronaut, Sch Business Adm, Zhengzhou 450046, Henan, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2018年 / 87卷

基金：

中国国家自然科学基金;

关键词：

Gadolinium(III); 3D polymer; Ferromagnetic behaviour; Magnetocaloric effect; SLOW MAGNETIC-RELAXATION; SINGLE-MOLECULE-MAGNET; LUMINESCENCE PROPERTIES; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURES; CLUSTERS; REFRIGERATION; COMPLEXES; GD; DERIVATIVES;

D O I：

10.1016/j.inoche.2017.11.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

One three-dimensional Gd(III) coordination polymer with 1,2-phenylenediacetate (PDA(2-)), [Gd-2(PDA)(3)(H2O)(2)].3H(2)O (1), has been successfully synthesized and characterized. Single-crystal X-ray diffraction analysis shows that 1 consists of 1D wave Gd-based chain unit and PDA(2-)linker. Magnetic studies suggest the presence of ferromagnetic Gd-Gd coupling in the 1D chain unit of 1. Meanwhile, 1 has a significant cryogenic magnetocaloric effect with the maximum -Delta S-m of 33.44 at 2K and 7T. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：20 / 23

页数：4

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