Hydrogen Production via Sorption Enhanced Steam Reforming of Acetic Acid: A Thermodynamic Study

被引：2
|
作者：
Fu, Peng [1 ]
Yi, Weiming [1 ]
Li, Zhihe [1 ]
Bai, Xueyuan [1 ]
机构：
[1] Shandong Univ Technol, Sch Agr & Food Engn, Zibo 255049, Peoples R China
来源：
APPLIED ENERGY TECHNOLOGY, PTS 1 AND 2 | 2013年 / 724-725卷
关键词：
Acetic acid; Steam reforming; Hydrogen production; Sorption enhanced; FUEL-CELLS;
D O I：
10.4028/www.scientific.net/AMR.724-725.769
中图分类号：
TU [建筑科学];
学科分类号：
0813 ;
摘要：
The reaction thermodynamics of sorption enhanced steam reforming (SESR) of acetic acid as a model compound of bio-oil for hydrogen production were investigated and contrasted with acetic acid steam reforming (SR). The most favorable temperature for SR is approximately 650 degrees C. However, the optimum temperature for SESR is around 550 degrees C, which is about 100 degrees C lower than that for SR. The highest hydrogen concentration from SR is only 67%, which is below the basic requirement of hydrogen purity for fuel cells. In SESR, hydrogen purities are over 99% in 500-550 degrees C with a calcium oxide to acetic acid molar ratio (CAMR) of 4 and a water to acetic acid molar ratio (WAMR) greater than 6. The results show that hydrogen production from sorption enhanced steam reforming of acetic acid should be a promising direction.
引用
收藏
页码：769 / 772
页数：4
相关论文
共 50 条
  • [1] Thermodynamic analysis of hydrogen production via steam reforming of acetic acid
    An, Senmeng
    Fu, Peng
    Yi, Weiming
    [J]. Taiyangneng Xuebao/Acta Energiae Solaris Sinica, 2013, 34 (09): : 1526 - 1530
  • [2] Hydrogen production via sorption enhanced steam reforming of butanol: Thermodynamic analysis
    Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China
    不详
    [J]. Int J Hydrogen Energy, 1600, 4 (2887-2895):
  • [3] Hydrogen production via sorption enhanced steam reforming of butanol: Thermodynamic analysis
    Wang, Wenju
    Cao, Yingyu
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (04) : 2887 - 2895
  • [4] Steam Reforming of Acetic Acid for Hydrogen Production: Thermodynamic Calculations
    Guo, Long
    Li, Xinbao
    Wang, Qi
    Wang, Shurong
    [J]. ADVANCED RESEARCH ON MATERIAL SCIENCE AND ENVIRONMENTAL SCIENCE, 2012, 534 : 141 - +
  • [5] Thermodynamic analysis of acetic acid steam reforming for hydrogen production
    Goicoechea, Saioa
    Ehrich, Heike
    Arias, Pedro L.
    Kockmann, Norbert
    [J]. JOURNAL OF POWER SOURCES, 2015, 279 : 312 - 322
  • [6] Thermodynamic Investigation of Acetic Acid Steam Reforming for Hydrogen Production
    Fu, Peng
    An, Senmeng
    Yi, Weiming
    Bai, Xueyuan
    [J]. ADVANCES IN CHEMICAL ENGINEERING II, PTS 1-4, 2012, 550-553 : 2801 - 2804
  • [7] Hydrogen production by sorption enhanced steam reforming of propane: A thermodynamic investigation
    Wang, Xiaodong
    Wang, Na
    Wang, Liang
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (01) : 466 - 472
  • [8] Thermodynamic study for hydrogen production from bio-oil via sorption-enhanced steam reforming: Comparison with conventional steam reforming
    Xie, Huaqing
    Yu, Qingbo
    Lu, Han
    Zhang, Yuanyuan
    Zhang, Jianrong
    Qin, Qin
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (08) : 28718 - 28731
  • [9] Simulation and exergetic evaluation of hydrogen production from sorption enhanced and conventional steam reforming of acetic acid
    Tian, Xingtao
    Wang, Shurong
    Zhou, Jinsong
    Xiang, Yangyang
    Zhang, Fan
    Lin, Bowen
    Liu, Sunan
    Luo, Zhongyang
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2016, 41 (46) : 21099 - 21108
  • [10] Comparative analysis on sorption enhanced steam reforming and conventional steam reforming of hydroxyacetone for hydrogen production: Thermodynamic modeling
    Fu, Peng
    Yi, Weiming
    Li, Zhihe
    Li, Yanmei
    Wang, Jing
    Bai, Xueyuan
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (27) : 11893 - 11901
12345