Long-range deuterium-induced isotope effects on H-1 chemical shifts in cis- and trans-stilbene

被引：5
|
作者：
Novak, P
Meic, Z
VikicTopic, D
Sterk, H
机构：
[1] RUDJER BOSKOVIC INST, DEPT CHEM, ZAGREB, CROATIA
[2] KARL FRANZENS UNIV GRAZ, DEPT ORGAN CHEM, A-8101 GRAZ, AUSTRIA
来源：
JOURNAL OF MOLECULAR STRUCTURE | 1997年 / 410卷
关键词：
deuterium isotope effects; H-1; NMR; cis-stilbene; trans-stilbene; conformation;
D O I：
10.1016/S0022-2860(96)09679-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Deuterium isotope effects on olefinic proton chemical shifts in a series of deuterated cis- and trans-stilbene isotopomers have been determined and analysed. The effects exhibit conformational and solvent dependence. The sign and magnitude of the effects are governed by the additivity rule. An opposite trend between the effects at the olefinic proton and those previously observed at olefinic carbon has been found and discussed for closely related compounds. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：9 / 12
页数：4
相关论文
共 50 条
  • [1] LONG-RANGE DEUTERIUM ISOTOPE EFFECTS ON CHEMICAL SHIFTS
    ALLRED, AL
    WILK, WD
    [J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (06): : 273 - &
  • [2] LONG-RANGE DEUTERIUM-ISOTOPE EFFECTS ON H-1 CHEMICAL-SHIFTS IN SOME SIMPLE ORGANOMETALLIC COMPOUNDS
    WEI, YC
    WELLS, PR
    LAMBERT, LK
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 1986, 24 (08) : 659 - 662
  • [3] Conformational dependence of deuterium-induced isotope effects on the olefinic one-bond C-13-H-1 and three-bond H-1-H-2 coupling constants in cis- and trans-stilbene
    Novak, P
    Meic, Z
    Sterk, H
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1996, (11): : 2531 - 2536
  • [4] Deuterium isotope effects on C-13 chemical shifts in cis-stilbene
    Meic, Z
    Novak, P
    VikicTopic, D
    Smrecki, V
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 1996, 34 (01) : 36 - 41
  • [5] LONG-RANGE DEUTERIUM-ISOTOPE EFFECTS ON NMR CHEMICAL-SHIFTS IN BENZYLIC IONS
    FORSYTH, DA
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1981, 181 (MAR): : 215 - ORGN
  • [6] Long-range intrinsic and equilibrium deuterium isotope effects on F-19 chemical shifts
    Hansen, PE
    Bolvig, S
    BuvariBarcza, A
    Lycka, A
    [J]. ACTA CHEMICA SCANDINAVICA, 1997, 51 (08): : 881 - 888
  • [7] UNUSUALLY LARGE DEUTERIUM-ISOTOPE EFFECTS ON ONE-BOND C-13, H-1 COUPLING-CONSTANTS IN TRANS-STILBENE CHALLENGED
    ERNST, L
    [J]. ORGANIC MAGNETIC RESONANCE, 1984, 22 (12): : 789 - 791
  • [8] Deuterium-induced isotope effects on the 13C chemical shifts of α-D-glucose pentaacetate
    Perez-Hernandez, Nury
    Alvarez-Cisneros, Celina
    Cerda-Garcia-Rojas, Carlos M.
    Morales-Rios, Martha S.
    Joseph-Nathan, Pedro
    [J]. MAGNETIC RESONANCE IN CHEMISTRY, 2013, 51 (03) : 136 - 142
  • [9] CONFORMATIONAL AND LONG-RANGE LOW FIELD STERIC DEUTERIUM-ISOTOPE EFFECTS ON CARBON CHEMICAL-SHIFTS
    PEHK, T
    LAHT, A
    LIPPMAA, E
    [J]. ORGANIC MAGNETIC RESONANCE, 1982, 19 (01): : 21 - 23
  • [10] LONG-RANGE DEUTERIUM-ISOTOPE EFFECT ON A LANTHANIDE INDUCED CHEMICAL-SHIFT
    DEPUY, CH
    FUNFSCHILLING, PC
    OLSON, JM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (01) : 276 - 278
12345