New Tetracyclic Spiro-1,2,4-trioxolanes (Ozonides). Synthesis and Mass Spectrometric Study

被引：5
|
作者：
Akimova, T. I. [1 ]
Rybin, V. G. [2 ]
Soldatkina, O. A. [1 ]
机构：
[1] Far Eastern Fed Univ, Ul Sukhanova 8, Vladivostok 690091, Russia
[2] Russian Acad Sci, Far Eastern Branch, Zhirmunskii Inst Marine Biol, Ul Palchevskogo 17, Vladivostok 690041, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 55卷 / 01期
关键词：
alicyclic 1,5-diketones; hydrogen peroxide; spiro-1,2,4-trioxolanes; tetracyclic ozonides; mass spectrometry; atmospheric pressure chemical ionization; quasi-molecular ions; ANTIMALARIAL; PEROXIDES; SPIRO;
D O I：
10.1134/S1070428019010123
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
New tetracyclic dispiro-1,2,4-trioxolanes (ozonides) were synthesized by reactions of 5-7-membered alicyclic 1,5-diketones with 30% hydrogen peroxide in diethyl ether or ethanol in the presence of boron trifluoride-diethyl ether complex or a strong mineral acid (HCl, H2SO4, HClO4). Mass spectrometric study of the title compounds under atmospheric pressure chemical ionization revealed specificity of fragment ion decomposition with respect to the ring size, which makes it possible to identify such compounds by their mass spectra.
引用
收藏
页码：101 / 107
页数：7
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