Aqua(dicyanamido){μ-6,6′-dimethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)sodium(I)

被引:1
|
作者
Shen, Yong-Miao [2 ]
Wang, Wei [1 ]
机构
[1] Yancheng Inst Technol, Sch Chem & Biol Engn, Yancheng 224003, Peoples R China
[2] Shaoxing Univ, Dept Chem, Shaoxing 312000, Peoples R China
关键词
D O I
10.1107/S1600536809011064
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The molecule of the title compound, [CuNa(C18H18N2O4)(C2N3)(H2O)], is almost planar, the maximum deviation from the molecular plane being 0.48 (4) angstrom. The coordination environment of the Cu2+ ion is distorted square-planar and it is N2O2-chelated by the Schiff base ligand. The Na+ cation has a distorted octahedral environment defined by the four O atoms of the 6,6'-dimethoxy-2,2'-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand, a water ligand and a dicyanamide anion.
引用
收藏
页码:M472 / U1155
页数:10
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