Enhancement and extinction effects in surface-enhanced stimulated Raman spectroscopy

被引：9
|
作者：
Chng, B. X. K. [1 ,2 ]
van Dijk, T. [1 ]
Bhargava, R. [1 ,3 ]
Carney, P. S. [1 ,2 ]
机构：
[1] Univ Illinois, Beckman Inst Adv Sci & Technol, Urbana, IL 61801 USA
[2] Univ Illinois, Dept Elect & Comp Engn, Urbana, IL 61801 USA
[3] Univ Illinois, Dept Bioengn, Urbana, IL 61801 USA
来源：
PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2015年 / 17卷 / 33期
关键词：
SCATTERING; PARTICLES; PROBES; MODEL; SERS;
D O I：
10.1039/c4cp05089d
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We address the optical physics of surface-enhanced stimulated Raman spectroscopy (SESRS) from the microscopic to macroscopic scales to provide experimental design criteria in colloidal-suspension SESRS. The nanoparticles that provide local field enhancement also extinguish the Raman signal. We compute the total Raman signal detected from a suspension of Raman-active molecules and nanoparticles due to the cumulative effects of enhancement and extinction and find optimum operating parameters for pump frequency and nanoparticle concentration.
引用
收藏
页码：21348 / 21355
页数：8
相关论文
共 50 条
  • [1] Balancing the Effects of Extinction and Enhancement for Optimal Signal in Surface-Enhanced Femtosecond Stimulated Raman Spectroscopy
    Gruenke, Natalie L.
    McAnally, Michael O.
    Schatz, George C.
    Van Duyne, Richard P.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (51): : 29449 - 29454
  • [2] Competition Between Extinction and Enhancement in Surface-Enhanced Raman Spectroscopy
    van Dijk, Thomas
    Sivapalan, Sean T.
    DeVetter, Brent M.
    Yang, Timothy K.
    Schulmerich, Matthew V.
    Murphy, Catherine J.
    Bhargava, Rohit
    Carney, P. Scott
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2013, 4 (07): : 1193 - 1196
  • [3] Surface-Enhanced Femtosecond Stimulated Raman Spectroscopy
    Frontiera, Renee R.
    Henry, Anne-Isabelle
    Gruenke, Natalie L.
    Van Duyne, Richard P.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (10): : 1199 - 1203
  • [4] Surface-enhanced stimulated Raman spectroscopy with squeezed photonic states
    Hagelberg, Frank
    Passian, Ali
    PHYSICAL REVIEW A, 2025, 111 (01)
  • [5] Enhanced Studying Stimulated Raman Activity in Surface-Enhanced Femtosecond Stimulated Raman Spectroscopy by Varying the Excitation Wavelength
    Buchanan, Lauren E.
    McAnally, Michael O.
    Gruenke, Natalie L.
    Schatz, George C.
    Van Duyne, Richard P.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (14): : 3328 - 3333
  • [6] Towards a traceable enhancement factor in surface-enhanced Raman spectroscopy
    Cara, Eleonora
    Mandrile, Luisa
    Sacco, Alessio
    Giovannozzi, Andrea M.
    Rossi, Andrea M.
    Celegato, Federica
    De Leo, Natascia
    Hoenicke, Philipp
    Kayser, Yves
    Beckhoff, Burkhard
    Marchi, Davide
    Zoccante, Alberto
    Cossi, Maurizio
    Laus, Michele
    Boarino, Luca
    Lupi, Federico Ferrarese
    JOURNAL OF MATERIALS CHEMISTRY C, 2020, 8 (46) : 16513 - 16519
  • [7] Surface-enhanced Raman spectroscopy
    Nature Reviews Methods Primers, 1
  • [8] Surface-enhanced Raman Spectroscopy
    Tomoaki Nishino
    Analytical Sciences, 2018, 34 : 1061 - 1062
  • [9] Surface-enhanced Raman spectroscopy
    Jürgen Popp
    Thomas Mayerhöfer
    Analytical and Bioanalytical Chemistry, 2009, 394 : 1717 - 1718
  • [10] Surface-Enhanced Raman Spectroscopy
    Stiles, Paul. L.
    Dieringer, Jon A.
    Shah, Nilain C.
    Van Duyne, Richard R.
    ANNUAL REVIEW OF ANALYTICAL CHEMISTRY, 2008, 1 (601-626) : 601 - 626
12345