Excited state intramolecular redox reaction of 2-(hydroxymethyl) anthraquinone in aqueous solution

被引：27
|
作者：
Lukeman, M [1 ]
Xu, MS [1 ]
Wan, P [1 ]
机构：
[1] Univ Victoria, Dept Chem, Victoria, BC V8W 3V6, Canada
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 02期
关键词：
D O I：
10.1039/b108746k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound undergoes a novel excited state intramolecular redox reaction in which the 'distal' side chain benzylic alcohol is oxidized to the aldehyde and the carbonyl moieties of anthraquinone reduced, with evidence suggesting that the primary photochemical process is a deprotonation of the benzylic C-H proton (by water) mediated by the solvent.
引用
收藏
页码：136 / 137
页数：2
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