Functionalized Cellulosic Fibers for Removal of Toxic Metal Ions From Contaminated Water

被引：5

作者：

Singha, A. S. ^{[1
]}

Guleria, Ashish ^{[1
]}

机构：

[1] Natl Inst Technol, Dept Chem, Hamirpur 177005, HP, India

来源：

INTERNATIONAL JOURNAL OF POLYMER ANALYSIS AND CHARACTERIZATION | 2014年 / 19卷 / 01期

关键词：

Cellulosic fiber; Toxic metal ion; Graft copolymer; Adsorption isotherm; Adsorption kinetics; AQUEOUS-SOLUTIONS; WASTE-WATER; ADSORPTION; ADSORBENTS;

D O I：

10.1080/1023666X.2014.850910

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Functionalization of cellulosic okra fibers was carried out by graft copolymerization of acrylamide in the presence of ascorbic acid and hydrogen peroxide as redox initiator in aqueous medium. Different reaction parameters such as time, temperature, initiator concentration, and monomer concentration were optimized to obtain the maximum graft yield. The graft copolymerized fibers were characterized by FT-IR, TGA, and X-ray diffraction techniques. Further, chemically modified fibers were used for removal of Zn2+ and Cd2+ toxic metal ions from contaminated water. The effect of pH, contact time, and metal ion concentration was studied in batch mode experiments. The kinetics of adsorption were studied using pseudo-first and pseudo-second-order kinetic models. The adsorption isotherm was studied using Langmuir and Freundlich isotherm models. The Langmuir model was found to fit the equilibrium data well.

引用

页码：10 / 21

页数：12

共 50 条

[1] Application of vinyl monomers functionalized cellulosic biopolymer for removal of dissolved toxic metal ions from polluted water samples
Singha, A. S.
Guleria, Ashish
[J]. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2014, 2 (03): : 1456 - 1466
[2] Adsorptive and kinetic studies of toxic metal ions from contaminated water by functionalized silica
Kumar, Rajesh
Verma, Sunita
Harwani, Geeta
Patidar, Deepesh
Mishra, Sanjit
[J]. MEMBRANE AND WATER TREATMENT, 2022, 13 (05): : 227 - 233
[3] Metal Ions Removal from Contaminated Water Using Membranes Functionalized with Ionic Liquids
Lupa, Lavinia
Cocheci, Laura
Dobos, Adina Maria
Onofrei, Mihaela Dorina
Negrea, Petru
Filimon, Anca
[J]. WATER, 2022, 14 (24)
[4] Iminodiacetic acid-functionalized porous polymer for removal of toxic metal ions from water
Anito, Dejene Assefa
Wang, Tian-Xiong
Liu, Zhi-Wei
Ding, Xuesong
Han, Bao-Hang
[J]. JOURNAL OF HAZARDOUS MATERIALS, 2020, 400
[5] STUDIES IN KINETICS OF REMOVAL OF WATER FROM CELLULOSIC FIBERS
DARUWALLA, EH
SHET, RT
[J]. JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1964, 2 (2PA): : 943 - &
[6] Adsorptive removal of metal ions from water using functionalized biomaterials
[J]. Deshpande, Kanchanmala (kanchanmala@unigoa.ac.in), 2017, Bentham Science Publishers (11)
[7] Adsorptive removal of multiple metal ions from contaminated water with EDTA functionalized superparamagnetic nanoparticles: Equilibrium, kinetics and thermodynamics
Huang, Yuxiong
Keller, Arturo
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
[8] Removal of toxic heavy metal ions from waste water by functionalized magnetic core–zeolitic shell nanocomposites as adsorbents
Mohsen Padervand
Mohammad Reza Gholami
[J]. Environmental Science and Pollution Research, 2013, 20 : 3900 - 3909
[9] Removal of Toxic Metal Ions From Potable Water by Graphene Oxide Composites
Gohel, Vishal D.
Rajput, Abhishek
Gahlot, Swati
Kulshrestha, Vaibhav
[J]. MACROMOLECULAR SYMPOSIA, 2017, 376 (01)
[10] REMOVAL OF TOXIC METALS AND NONMETALS FROM CONTAMINATED WATER
BARTZATT, R
CANO, M
JOHNSON, L
NAGEL, D
[J]. JOURNAL OF TOXICOLOGY AND ENVIRONMENTAL HEALTH, 1992, 35 (04): : 205 - 210

← 1 2 3 4 5 →