Synthesis of α,ω-differently substituted cyclic ethers from carbohydrates by β-fragmentation of alkoxyl radicals

被引：8
|
作者：
Boto, A [1 ]
Hernández, R [1 ]
Suárez, E [1 ]
机构：
[1] CSIC, Inst Prod Nat & Agrobiol, San Cristobal de la Laguna 38206, Spain
来源：
TETRAHEDRON LETTERS | 2002年 / 43卷 / 10期
关键词：
alkoxyl radical; fragmentation carbohydrates; diastereoselective synthesise; alditols; cyclic ethers;
D O I：
10.1016/S0040-4039(02)00123-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The beta-fragmentation of alkoxyl radicals derived from easily available carbohydrates is a mild and efficient procedure to obtain unsymmetrical alpha,omega-disubstituted cyclic ethers. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1821 / 1824
页数：4
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