Selective formation of mono- and tetra-cycloadducts by the Diels-Alder reaction of [60]fullerene with 2,5-dimethylthiophene S-oxides

被引：0

作者：

Zeng, HP

Eguchi, S

机构：

[1] NAGOYA UNIV, GRAD SCH ENGN, DEPT MOL DESIGN & ENGN, CHIKUSA KU, NAGOYA, AICHI 46401, JAPAN

[2] S CHINA NORMAL UNIV, DEPT CHEM, GUANGZHOU 510631, PEOPLES R CHINA

来源：

SYNLETT | 1997年 / 02期

关键词：

thiophene S-oxides; Diels-Alder reaction; 60]fullerene;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2,5-Dimethylthiophene S-monoxide and S,S-dioxide prepared from the corresponding thiophene by BF3-Et(2)O catalyzed oxidation with m-CPBA reacted with fullerene C-60 at room temperature to produce specifically mono- and tetra-adduct respectively.

引用

页码：175 / +

共 5 条

[1] Formation and hetero Diels-Alder reaction of α-iminosulfines:: Synthesis of 5,6-dihydro-1,4-thiazine S-oxides
Capozzi, G
Menichetti, S
Nativi, C
Vergamini, C
SYNTHESIS-STUTTGART, 1998, (06): : 915 - 918
[2] HETERO-DIELS-ALDER REACTION OF FULLERENE - SYNTHESIS OF THIOCHROMAN-FUSED C-60 WITH O-THIOQUINONE METHIDE AND OXIDATION TO ITS S-OXIDES
OHNO, M
KOJIMA, S
SHIRAKAWA, Y
EGUCHI, S
TETRAHEDRON LETTERS, 1995, 36 (38) : 6899 - 6902
[3] C2-SYMMETRY-CHIRAL KETENE DITHIOACETALS DERIVED FROM 1,1'-BINAPHTHALENE-2,2'-DITHIOL - DIASTEREOSELECTIVE DIELS-ALDER REACTION OF THE S-OXIDES TO CYCLOPENTADIENE
DELUCCI, O
FABBRI, D
LUCCHINI, V
SYNLETT, 1991, (08) : 565 - 568
[4] (5R/5S)-2,5-diphenyl-7-[trans-(1R/1S,2S/2R)-2-phenylcyclohexyloxy]-2,3,5,8-tetrahydro-1H-1,2,4-triazolo[1,2-a]pyridazine-1,3-dione-water (1/1): a face-selective Diels-Alder reaction of 2-alkoxy-1,3-butadiene
Garcia-Granda, S
Santiago-Garcia, R
Suarez-Sobrino, A
Lopez, LA
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1997, 53 : 1941 - 1943
[5] (5R/5S)-2,5-Diphenyl-7-[trans- (1R/1S,2S/2R)-2-phenylcyclo hexyloxy]-2, 3,5,8-tetrahydro-1H-1,2,4-triazolo[ 1,2-a]pyridazine-1, 3-dione-water (1/1): A face-selective Diels-Alder reaction of 2-alkoxy-1,3-butadiene
Universidad de Oviedo, Oviedo, Spain
Acta Crystallogr Sect C Cryst Struct Commun, pt 12 (1941-1943):

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