Selective Palladium-Catalyzed Hydroformylation of Alkynes to ,-Unsaturated Aldehydes

被引：70
|
作者：
Fang, Xianjie [1 ]
Zhang, Min [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期
关键词：
alkynes; hydroformylation; hydrogenation; palladium; -unsaturated aldehydes; ZWITTERIONIC RHODIUM COMPLEX; REGIOSELECTIVE HYDROFORMYLATION; ALKOXYCARBONYLATION; ENYNES; METHOXYCARBONYLATION; MECHANISM; ALKENES; ETHENE;
D O I：
10.1002/anie.201300759
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Atom-efficient: A selective palladium catalyst system is used for the hydroformylation of alkynes (see picture). In this syngas reaction, various alkynes were smoothly transformed to synthetically interesting α,β-unsaturated aldehydes in good yields with high regio- and stereoselectivity. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：4645 / 4649
页数：5
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