Supported phosphine-free palladium catalysts for the Suzuki-Miyaura reaction in aqueous media

被引：58
|
作者：
Phan, Nam T. S. [1 ]
Styring, Peter [1 ]
机构：
[1] Univ Sheffield, Dept Chem & Proc Engn, Sheffield S1 3JD, S Yorkshire, England
来源：
GREEN CHEMISTRY | 2008年 / 10卷 / 10期
基金：
英国工程与自然科学研究理事会;
关键词：
D O I：
10.1039/b805290e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The Suzuki-Miyaura reaction has been performed using a non- symmetrical salen-type palladium(II) catalyst that is readily immobilized onto Merrifield resin and functionalized silica. The catalysts combine high activity with the recoverability and reusability offered by a heterogeneous system, without the need for phosphine ligands or additives. The high content of water used in the reaction, which is more than 96% by volume, represents a green process that should have advantages for industrial applications. Leaching of the metal into solution from the supported catalyst proved to be negligible.
引用
收藏
页码：1055 / 1060
页数：6
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