catena-Poly[[(1,10-phenanthroline)cadmium(II)]-μ-2-(1,3-benzimidazol-2-ylsulfanyl)acetato-κ3N1,O:N3]

被引：1
|
作者：
Cheng, Lin [1 ]
Sun, Yan-Yan [1 ]
Zhang, Ya-Wen [1 ]
Wang, Jian-Quan [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536808041044
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In title compound, [Cd(C9H6N2O2S)(C12H8N2)](n), the Cd-II atom is in a distorted tetragonal-pyramidal environment, coordinated by one chelating 1,10-phenanthroline ligand, one chelating 2-(1,3-benzimidazol-2-ylsulfanyl) acetate (bia) ligand bound through one N atom and one O atom of the carboxyl group, and one N atom from a second bia ligand. Each bia ligand acts as bridge between Cd-II ions, forming one-dimensional coordination polymers along [010], with a shortest Cd center dot center dot center dot Cd distance of 4.27 (2) angstrom.
引用
收藏
页码：M34 / U427
页数：9
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