Primary volcanic phenomena are potentially catastrophic, whilst those of a secondary nature may be merely considered as background activity but may be of sufficient intensity to cause long-term suffering to indigenous populations. The latter is the case at Poas volcano in Costa Rica, where a change in the quiescent state of the volcano has been shown by increasing activity during the last decade. Acid gases are apparently now being emitted more intensely than before, particularly during the dry season, to the detriment of the health of people and domestic livestock living in the surrounding countryside. Damage to crops and farm buildings is also evident. A pilot geochemical study has been undertaken at Poas volcano to determine the principal constituents of the gas emissions, the form in which they are most likely to be transported and the extent of the area within which they can be easily measured. The results obtained indicate that emissions of mixed volatile acids contribute to the problems encountered, and that, as might be expected, seasonal changes and distance from the source also exert control. Rainfall effectively scrubs the acid gases during the wet season, thereby considerably ameliorating the immediate effects of the emissions.