Adsorption of tetranitromethane in zeolitic imidazolate frameworks yields energetic materials

被引：14
|
作者：
Kent, Rosalyn V. [1 ]
Vaid, Thomas P. [1 ]
Boissonnault, Jake A. [1 ]
Matzger, Adam J. [1 ,2 ]
机构：
[1] Univ Michigan, Dept Chem, 930 N Univ Ave, Ann Arbor, MI 48109 USA
[2] Univ Michigan, Dept Macromol Sci & Engn, Ann Arbor, MI 48019 USA
来源：
DALTON TRANSACTIONS | 2019年 / 48卷 / 22期
关键词：
METAL-ORGANIC FRAMEWORKS; COORDINATION COPOLYMER; HE-MOFS; SENSITIVITY; THERMOSTABILITY; INSENSITIVITY; PERFORMANCE; COCRYSTALS; STABILITY; CHEMISTRY;
D O I：
10.1039/c9dt01254k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Porous frameworks consisting of functionalized imidazolate ligands and zinc nodes are employed as hosts for the oxidant tetra-nitromethane to produce energetic composite materials. This new class of energetic materials are achieved through the facile strategy of oxidant adsorption wherein fuel and oxidant are intimately mixed yielding a material that responds violently to thermal and impact stimuli.
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页码：7509 / 7513
页数：5
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