An oxamidato-bridged binuclear imidazole-copper(II) complex

被引:5
|
作者
Zhang, CG [1 ]
Sun, J
Kong, XF
Zhao, CX
机构
[1] Shanghai Jiao Tong Univ, Dept Chem, Shanghai 200030, Peoples R China
[2] Acad Sinica, Shanghai Inst Organ Chem, Shanghai 200232, Peoples R China
关键词
D O I
10.1107/S0108270199001110
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The oxpn ligand [oxpn = N, N'-bis(3- aminopropyl)oxamide] in the title compound, mu-[N,N'-bis(3-aminopropyl)oxamidato(2-)]-N,N',O':N ",N''',O-bis[(imidazole N-3)(nitrato-O)copper(II)], [Cu-2(C8H16N4O2)(NO3)(2)(C3H4N2)(2)], is bis-tridentate in a trans conformation, bridging two Cu-II ions to form a centrosymmetric binuclear molecule. The symmetry-equivalent central Cu-II ions are located in a distorted square-based pyramid, with an O atom from the nitrate ion bonded at the axial site, and a Cu ... Cu distance of 5.242 (2) Angstrom.
引用
收藏
页码:873 / 875
页数:3
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